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1. (WO2016057661) DEHYDROGENATION OF NEAT FORMIC ACID
Latest bibliographic data on file with the International Bureau   

Pub. No.: WO/2016/057661 International Application No.: PCT/US2015/054483
Publication Date: 14.04.2016 International Filing Date: 07.10.2015
IPC:
C07F 15/00 (2006.01) ,C07F 3/00 (2006.01) ,C07C 53/02 (2006.01) ,B01J 23/46 (2006.01)
Applicants: UNIVERSITY OF SOUTHERN CALIFORNIA[US/US]; 1150 South Olive Street Suite 2300 Los Angeles, California 90015, US
Inventors: WILLIAMS, Travis J.; US
CELAJE, Jeff Joseph A.; US
Agent: PROSCIA, James W.; US
Priority Data:
62/060,75307.10.2014US
62/192,42314.07.2015US
Title (EN) DEHYDROGENATION OF NEAT FORMIC ACID
(FR) DÉSHYDROGÉNATION D'ACIDE FORMIQUE PUR
Abstract: front page image
(EN) A formic acid decomposition catalyst system includes organometallic complexes having formula 1: (1) wherein: M is a transition metal; E is P, N, or C (as in imidazolium carbene); R1, R2 are independently C1-6 alkyl groups; o is 1, 2, 3, or 4; R3 are independently hydrogen, C1-6 alkyl groups, OR14, NO2, halogen; R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R15, R16 are independently hydrogen or C1-6 alkyl groups; R14 is a C1-6 alkyl group; and X- is a negatively charge counter ion.
(FR) La présente invention concerne un système catalyseur de décomposition d'acide formique qui comprend les complexes organométalliques ayant la formule 1 : (1) dans laquelle : M est un métal de transition; E est P, N, ou C (comme dans le carbène d'imidazolium) ; R1, R2 sont indépendamment des groupes alkyle en C1-6 ; o est 1, 2, 3, ou 4 ; R3 sont indépendamment un atome d'hydrogène, des groupes alkyle en C1-6, OR14, NO2, halogéno ; R4, R5, R6, R7, R8, R9, R10, R11, R12, R13, R15, R16 sont indépendamment un atome d'hydrogène ou des groupes alkyle en C1-6 ; R14 est un groupe alkyle en C1-6; et X- est un contre-ion de charge négative.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)