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1. (WO2016053017) PROCESS FOR PREPARING ALPHA-SILYLAMINE COMPOUNDS FROM ALPHA-SILYLMETHYL AZIDE COMPOUNDS

Pub. No.:    WO/2016/053017    International Application No.:    PCT/KR2015/010352
Publication Date: Fri Apr 08 01:59:59 CEST 2016 International Filing Date: Fri Oct 02 01:59:59 CEST 2015
IPC: C07F 7/10
B01J 31/28
C07C 241/00
Applicants: POSTECH ACADEMY-INDUSTRY FOUNDATION
포항공과대학교 산학협력단
Inventors: PARK, Jaiwook
박재욱
KIM, Jung Joon
김정준
JEONG, Wook
정욱
RHEE, Young Ho
이영호
Title: PROCESS FOR PREPARING ALPHA-SILYLAMINE COMPOUNDS FROM ALPHA-SILYLMETHYL AZIDE COMPOUNDS
Abstract:
The present invention relates to a process for preparing alpha-silylamine compounds and, more specifically, to a one-pot process for preparing various alpha-silylamine compounds by reacting, in the presence of a metal complex catalyst and under a mild condition, an alpha-silylmethyl azide compound as a starting material with various allylborate compounds via an alpha-silylimine intermediate which has no substituent at nitrogen.