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1. WO2016040012 - EMULSION POLYMERS INCLUDING ONE OR MORE 1,1-DISUBSTITUTED ALKENE COMPOUNDS, EMULSION METHODS, AND POLYMER COMPOSITIONS

Publication Number WO/2016/040012
Publication Date 17.03.2016
International Application No. PCT/US2015/047445
International Filing Date 28.08.2015
Chapter 2 Demand Filed 08.07.2016
IPC
C08L 31/00 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
31Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Compositions of derivatives of such polymers
CPC
B05D 3/007
BPERFORMING OPERATIONS; TRANSPORTING
05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
3Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
007After-treatment
C08F 2/06
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
04Polymerisation in solution
06Organic solvent
C08F 2/26
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
12Polymerisation in non-solvents
16Aqueous medium
22Emulsion polymerisation
24with the aid of emulsifying agents
26anionic
C08F 222/14
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
222Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
10Esters
12of phenols or saturated alcohols
14Esters having no free carboxylic acid groups ; , e.g. dialkyl maleates or fumarates
C08F 297/02
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
297Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
02using a catalyst of the anionic type
C09D 135/02
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
135Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least another carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Coating compositions based on derivatives of such polymers
02Homopolymers or copolymers of esters
Applicants
  • SIRRUS, INC. [US]/[US]
Inventors
  • STEVENSON, Peter, R.
  • HOLZER, Alexander, R.
  • PALSULE, Aniruddha, S.
  • SULLIVAN, Jeffrey M.
Agents
  • FINERMAN, Terry, M.
Priority Data
14/789,17801.07.2015US
14/810,74128.07.2015US
62/047,28308.09.2014US
62/047,32808.09.2014US
62/182,07619.06.2015US
62/186,47930.06.2015US
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) EMULSION POLYMERS INCLUDING ONE OR MORE 1,1-DISUBSTITUTED ALKENE COMPOUNDS, EMULSION METHODS, AND POLYMER COMPOSITIONS
(FR) POLYMÈRES EN ÉMULSION COMPRENANT UN OU PLUSIEURS COMPOSÉS D'ALCÈNE 1,1-DISUBSTITUÉ, PROCÉDÉS EN ÉMULSION, ET COMPOSITIONS DE POLYMÈRE
Abstract
(EN) The present teachings show that it is possible to polymerize 1,1-disubstituted alkene compounds in an emulsion (for example using a water based carrier liquid), despite the possible reactions between the monomer and water. Polymerization of 1,1-disubstituted alkene compounds in an emulsion provides opportunities to better control the polymerization compared with bulk polymerization. The emulsion polymerization techniques can be employed for preparing homopolymers, copolymers (e.g., random copolymers), and block copolymers.
(FR) La présente invention montre qu'il est possible de polymériser des composés d'alcène 1,1-disubstitué dans une émulsion (par exemple, au moyen d'un liquide véhicule à base d'eau), malgré les réactions possibles entre le monomère et l'eau. La polymérisation de composés d'alcène 1,1-disubstitué dans une émulsion offre des opportunités d’une meilleure régulation de la polymérisation par rapport à la polymérisation en masse. Les techniques de polymérisation en émulsion peuvent être utilisées pour préparer des homopolymères, des copolymères (par exemple, des copolymères statistiques), et des copolymères séquencés.
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