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1. WO2016030790 - OXIME SULFONATE DERIVATIVES

Publication Number WO/2016/030790
Publication Date 03.03.2016
International Application No. PCT/IB2015/056177
International Filing Date 13.08.2015
IPC
C07D 213/59 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
213Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
02having three double bonds between ring members or between ring members and non-ring members
04having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
24with substituted hydrocarbon radicals attached to ring carbon atoms
54Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals
59with at least one of the bonds being to sulfur
C07D 265/32 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
265Heterocyclic compounds containing six-membered rings having one nitrogen atom and one oxygen atom as the only ring hetero atoms
281,4-Oxazines; Hydrogenated 1,4-oxazines
30not condensed with other rings
32with oxygen atoms directly attached to ring carbon atoms
C07D 277/54 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
277Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
02not condensed with other rings
20having two or three double bonds between ring members or between ring members and non-ring members
32with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
54Nitrogen and either oxygen or sulfur atoms
C07D 291/02 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
291Heterocyclic compounds containing rings having nitrogen, oxygen and sulfur atoms as the only ring hetero atoms
02not condensed with other rings
C07D 327/06 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
327Heterocyclic compounds containing rings having oxygen and sulfur atoms as the only ring hetero atoms
02one oxygen atom and one sulfur atom
06Six-membered rings
C07C 309/30 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
309Sulfonic acids; Halides, esters, or anhydrides thereof
01Sulfonic acids
28having sulfo groups bound to carbon atoms of six-membered aromatic rings of a carbon skeleton
29of non-condensed six-membered aromatic rings
30of six-membered aromatic rings substituted by alkyl groups
CPC
C07C 2601/20
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2601Systems containing only non-condensed rings
18with a ring being at least seven-membered
20the ring being twelve-membered
C07C 327/58
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
327Thiocarboxylic acids
58Derivatives of thiocarboxylic acids, the doubly-bound oxygen atoms being replaced by nitrogen atoms, e.g. imino-thio ethers
C07D 209/48
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
209Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
02condensed with one carbocyclic ring
44Iso-indoles; Hydrogenated iso-indoles
48with oxygen atoms in positions 1 and 3, e.g. phthalimide
G02B 1/14
GPHYSICS
02OPTICS
BOPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
1Optical elements characterised by the material of which they are made
10Optical coatings produced by application to, or surface treatment of, optical elements
14Protective coatings, e.g. hard coatings
G02B 5/201
GPHYSICS
02OPTICS
BOPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
5Optical elements other than lenses
20Filters
201in the form of arrays
G02B 5/223
GPHYSICS
02OPTICS
BOPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
5Optical elements other than lenses
20Filters
22Absorbing filters
223containing organic substances, e.g. dyes, inks or pigments
Applicants
  • BASF SE [DE]/[DE]
  • BASF (CHINA) COMPANY LIMITED [CN]/[CN] (MN)
Inventors
  • KUNIMOTO, Kazuhiko
  • SAMESHIMA, Kaori
  • KURA, Hisatoshi
  • MATSUOKA, Yuki
Agents
  • MAIWALD PATENTANWALTS GMBH
Priority Data
14182828.529.08.2014EP
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) OXIME SULFONATE DERIVATIVES
(FR) DÉRIVÉS DE SULFONATE D'OXIME
Abstract
(EN) Oxime sulfonate compounds of the formula (I), wherein R 1 is O(CO)R 4, COOR 5 or CONR 6R 7; n is 1 or 2; R 2 for example is C 1-C 8alkyl, C 3-C 6cycloalkyl or benzyl; R 3 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 4 is for example C 1-C 8alkyl, C 3-C 6cycloalkyl, C 1-C 8haloalkyl, C 2-C 8alkenyl, benzyl, phenyl or naphthyl, which optionally are substituted; R 5 is for example C 3-C 20alkyl, C 3-C 14cycloalkyl, C 2-C 8alkenyl, C 1-C 12alkyl which is substituted for example by one or more halogen; or R 5 is phenyl or naphthyl, which are unsubstituted; R 6 and R 7 each independently of one another for example are hydrogen, C 1-C 12alkyl, C 1-C 4haloalkyl, phenyl-C 1-C 4alkyl, C 2-C 8alkenyl or C 3-C 6cycloalkyl, phenyl or naphthyl; or R 6 and R 7, together with the N-atom to which they are attached, form a 5- or 6-membered ring; are suitable as thermal radical initiators.
(FR) La présente invention concerne des composés de sulfonate d'oxime de formule I, dans laquelle R 1 est O(CO)R 4, COOR 5 ou CONR 6R 7; n est 1 ou 2; R 2 est par exemple un groupe alkyle en C 1-C 8, un groupe cycloalkyle ou benzyle en C 3-C 6; R 3 est par exemple un groupe alkyle en C 1-C 8, un groupe cycloalkyle en C 3-C 6, un groupe halogénoalkyle en C 1-C 8, un groupe alcényle, benzyle, phényle ou naphtyle en C 2-C 8, qui sont facultativement substitués; R 4 est par exemple un groupe alkyle en C 1-C 8, un groupe cycloalkyle en C 3-C 6, un groupe halogénoalkyle en C 1-C 8, un groupe alcényle, benzyle, phényle ou naphtyle en C 2-C 8, qui sont facultativement substitués; R 5 est par exemple un groupe alkyle en C 3-C 20, un groupe cycloalkyle en C 3-C 14, un groupe alcényle en C 2-C 8, un groupe alkyle en C 1-C 12 qui est remplacé par exemple par au moins un halogène; ou R 5 est un groupe phényle ou naphtyle, qui ne sont pas substitués; R 6 et R 7 sont indépendamment l'un de l'autre hydrogène, un groupe alkyle en C 1-C 12, un groupe halogénoalkyle en C 1-C 4, un groupe phényle-C 1-C 4alkyle, un groupe alcényle en C 2-C 8 ou un groupe cycloalkyle, phényle, ou naphtyle en C 3-C 6; ou R 6 et R 7, conjointement avec l'atome N auquel ils sont fixés, forment un cycle à 5 ou 6 chaînons; sont appropriés en tant qu'initiateurs radicalaires thermiques.
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