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1. WO2015081918 - A METHOD AND DEVICE FOR FATIGUE TESTING OF PHOTOCHROMIC, FLUORESCENT OR PHOSPHORESCENT DYES

Publication Number WO/2015/081918
Publication Date 11.06.2015
International Application No. PCT/CZ2014/000144
International Filing Date 02.12.2014
IPC
G01N 33/36 2006.1
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
33Investigating or analysing materials by specific methods not covered by groups G01N1/-G01N31/131
36Textiles
G01N 17/00 2006.1
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
17Investigating resistance of materials to the weather, to corrosion or to light
G01N 21/64 2006.1
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
21Investigating or analysing materials by the use of optical means, i.e. using infra-red, visible or ultra-violet light
62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
63optically excited
64Fluorescence; Phosphorescence
CPC
G01J 3/50
GPHYSICS
01MEASURING; TESTING
JMEASUREMENT OF INTENSITY, VELOCITY, SPECTRAL CONTENT, POLARISATION, PHASE OR PULSE CHARACTERISTICS OF INFRA-RED, VISIBLE OR ULTRA-VIOLET LIGHT; COLORIMETRY; RADIATION PYROMETRY
3Spectrometry; Spectrophotometry; Monochromators; Measuring colours
46Measurement of colour; Colour measuring devices, e.g. colorimeters
50using electric radiation detectors
G01N 17/004
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
17Investigating resistance of materials to the weather, to corrosion, or to light
004to light
G01N 21/6428
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
21Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
63optically excited
64Fluorescence; Phosphorescence
6428Measuring fluorescence of fluorescent products of reactions or of fluorochrome labelled reactive substances, e.g. measuring quenching effects, using measuring "optrodes"
G01N 21/645
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
21Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
62Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
63optically excited
64Fluorescence; Phosphorescence
645Specially adapted constructive features of fluorimeters
G01N 2201/061
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
2201Features of devices classified in G01N21/00
06Illumination; Optics
061Sources
G01N 2201/08
GPHYSICS
01MEASURING; TESTING
NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
2201Features of devices classified in G01N21/00
08Optical fibres; light guides
Applicants
  • TECHNICKA UNIVERZITA V LIBERCI [CZ]/[CZ]
Inventors
  • VIK, Michal
  • VIKOVA, Martina
Agents
  • MUSIL, Dobroslav
Priority Data
PV 2013-95903.12.2013CZ
Publication Language English (en)
Filing Language Czech (CS)
Designated States
Title
(EN) A METHOD AND DEVICE FOR FATIGUE TESTING OF PHOTOCHROMIC, FLUORESCENT OR PHOSPHORESCENT DYES
(FR) PROCÉDÉ ET DISPOSITIF D'ESSAI DE FATIGUE DE COLORANTS PHOTOCHROMES, FLUORESCENTS OU PHOSPHORESCENTS
Abstract
(EN) The invention relates to a method for fatigue testing of photochromic, fluorescent or phosphorescent dye/dyes or of a mixture of at least two of them, in which a sample (3) containing photochromic, fluorescent or phosphorescent dye/dyes or a mixture of at least two of them is exposed to a predetermined number of cycles of luminous exposure to an excitation light beam (81), which evokes a color response of the photochromic, fluorescent or phosphorescent dye/dyes or of the mixture of at least two of them in the sample (3). Before and/or during and/or after each predetermined exposure to the excitation light beam (81), the sample (3) containing the photochromic, fluorescent or phosphorescent dye/dyes or of the mixture of at least two of them is exposed at least once to irradiation by an exposure light beam (71), due to which the dye/dyes is/are subject to fatigue loading. Simultaneously, a measuring light beam (41) is introduced to the sample (3) and is reflected from it, whereby the change and/or the course of the change in the characteristics of the measuring light beam (41) reflected from the sample is monitored by a spectrometer (94). From this change and/or the course of the change it is possible to deduce the course of the color response and/or the change in the color response of the particular photochromic, fluorescent or phosphorescent dye/dyes or of the mixture of at least two of them in the sample (3) to the exposure to an excitation light beam (81) and thus it is possible to deduce the fatigue of this photochromic, fluorescent or phosphorescent dye/dyes or of the mixture of at least two of them. The invention also relates to a device for carrying out this method.
(FR) La présente invention concerne un procédé d'essai de fatigue d'un ou plusieurs colorants photochromes, fluorescents ou phosphorescents ou d'un mélange d'au moins deux d'entre eux, selon lequel un échantillon (3) contenant un ou plusieurs colorants photochromes, fluorescents ou phosphorescents ou un mélange d'au moins deux d'entre eux est exposé à un nombre prédéfini de cycles d'exposition lumineuse à un faisceau de lumière d'excitation (81), ce qui provoque une sensibilité chromatique du ou des colorants photochromes, fluorescents ou phosphorescents ou du mélange d'au moins deux d'entre eux dans l'échantillon (3). Avant et/ou pendant et/ou après chaque exposition prédéfinie au faisceau de lumière d'excitation (81), l'échantillon (3) contenant le ou les colorants photochromes, fluorescents ou phosphorescents ou le mélange d'au moins deux d'entre eux est exposé au moins une fois au rayonnement d'un faisceau de lumière d'exposition (71), en raison duquel le ou les colorants sont soumis à une charge de fatigue. Simultanément, un faisceau de lumière de mesure (41) est introduit dans l'échantillon (3) et il est réfléchi à partir de ce dernier, moyennant quoi le changement et/ou l'évolution du changement des caractéristiques du faisceau de lumière de mesure (41) réfléchi à partir de l'échantillon sont surveillés par un spectromètre (94). A partir de ce changement et/ou de l'évolution du changement, il est possible de déduire l'évolution de la sensibilité chromatique et/ou le changement de la sensibilité chromatique du ou des colorants photochromes, fluorescents ou phosphorescents particuliers ou du mélange d'au moins deux d'entre eux dans l'échantillon (3) à l'exposition à un faisceau de lumière d'excitation (81) et il est ainsi possible de déduire la fatigue dudit ou desdits colorants photochromes, fluorescents ou phosphorescents ou du mélange d'au moins deux d'entre eux. L'invention concerne également un dispositif destiné à mettre en œuvre ledit procédé.
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