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1. WO2014125555 - COPOLYMER AND MOLDED BODY

Publication Number WO/2014/125555
Publication Date 21.08.2014
International Application No. PCT/JP2013/007696
International Filing Date 27.12.2013
IPC
C08F 230/02 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
230Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium, or a metal
02containing phosphorus
CPC
C08F 212/08
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
212Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
02Monomers containing only one unsaturated aliphatic radical
04containing one ring
06Hydrocarbons
08Styrene
C08F 220/10
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
C08F 220/14
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
12of monohydric alcohols or phenols
14Methyl esters ; , e.g. methyl (meth)acrylate
C08F 220/68
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
62Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
68Esters
C08F 230/02
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
230Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
02containing phosphorus
Applicants
  • 株式会社クラレ KURARAY CO., LTD. [JP]/[JP]
Inventors
  • 阿部 達 ABE, Toru
  • 中原 淳裕 NAKAHARA, Atsuhiro
  • 小西 啓之 KONISHI, Hiroyuki
  • 小澤 宙 OZAWA, Hiroshi
Agents
  • 菊間 忠之 KIKUMA, Tadayuki
Priority Data
2013-02906618.02.2013JP
2013-14021903.07.2013JP
Publication Language Japanese (ja)
Filing Language Japanese (JA)
Designated States
Title
(EN) COPOLYMER AND MOLDED BODY
(FR) COPOLYMÈRE ET CORPS MOULÉ
(JA) 共重合体および成形体
Abstract
(EN) Provided is a copolymer which contains a structural unit (I) derived from a phosphonate-based monomer (1) such as diethylmethacryloyloxymethyl phosphonate or diethyl-2-methacryloyloxyethyl phosphonate and a structural unit (II) derived from a radically polymerizable monomer (2) such as methacrylic acid, acrylic acid, 8-tricyclo[5.2.1.02,6]decanyl methacrylate or t-butyl methacrylate, and in which the content of phosphorus atoms derived from the phosphonate-based monomer (1) is 2.0-6.0 mass % relative to the mass of the copolymer. Also provided is a molded body that contains this copolymer.
(FR) L'invention porte sur un copolymère qui contient un motif de structure (I) issu d'un monomère à base de phosphonate (1), tel que le phosphonate de diéthylméthacryloyloxyméthyle ou le phosphonate de diéthyl-2-méthacryloyloxyéthyle, et un motif de structure (II) issu d'un monomère polymérisable par voie radicalaire (2) tel que l'acide méthacrylique, l'acide acrylique, le méthacrylate de 8-tricyclo[5.2.1.02,6]décanyle ou le méthacrylate de t-butyle, la teneur en atomes de phosphore issus du monomère à base de phosphonate (1) étant de 2,0-6,0 % en masse par rapport à la masse du copolymère. L'invention porte également sur un corps moulé qui contient ce copolymère.
(JA)  ジエチルメタクリロイルオキシメチルホスホネート、ジエチル 2-メタクリロイルオキシエチルホスホネートなどのホスホネート系単量体(1)に由来する構造単位(I)と、 メタクリル酸、アクリル酸、メタクリル酸8-トリシクロ[5.2.1.02,6]デカニル、メタクリル酸t-ブチルなどのラジカル重合性単量体(2)に由来する構造単位(II)とを含有し、且つ 前記ホスホネート系単量体(1)に由来するリン原子の含有量が共重合体の質量に対して2.0~6.0質量%である、共重合体。該共重合体を含有する成形体。
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