Identification devices (e.g., wristbands) including a face stock comprising a tough polyolefin material and a flexible vinyl layer are provided. A direct thermal chemistry layer can be deposited directly onto a top surface of the face stock or alternatively a pre-print color layer can be depositing directly onto the top surface of the face stock and the direct thermal chemistry layer can be deposited / located onto the free side of the pre-print layer. The flexible vinyl layer can be adhered to a bottom side of the face stock via an adhesive tie-layer sandwiched between the bottom side of the face stock and the flexible vinyl layer. If desired, an anti-cling layer can also be incorporated into the identification devices.