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1. WO2013011693 - LIGHT-CURING RESIN COMPOSITION, AND PLUMBING MEMBER AND FUNCTIONAL PANEL USING SAME

Publication Number WO/2013/011693
Publication Date 24.01.2013
International Application No. PCT/JP2012/004602
International Filing Date 19.07.2012
IPC
C08F 290/06 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
290Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
02on to polymers modified by introduction of unsaturated end groups
06Polymers provided for in subclass C08G52
C08F 299/06 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
299Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
02from unsaturated polycondensates
06from polyurethanes
C09D 4/02 2006.01
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
4Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
02Acrylmonomers
C09D 7/12 2006.01
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
7Features of coating compositions, not provided for in group C09D5/88; Processes for incorporating ingredients in coating compositions
12Other additives
C09D 175/16 2006.01
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
175Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
04Polyurethanes
14Polyurethanes having carbon-to-carbon unsaturated bonds
16having terminal carbon-to-carbon unsaturated bonds
C09D 183/07 2006.01
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
183Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
04Polysiloxanes
07containing silicon bound to unsaturated aliphatic groups
CPC
C08F 230/08
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
230Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
04containing a metal
08containing silicon
C08F 290/068
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
290Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
02on to polymers modified by introduction of unsaturated end groups
06Polymers provided for in subclass C08G
068Polysiloxanes
C08F 299/06
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
299Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
02from unsaturated polycondensates
06from polyurethanes
C08G 18/4833
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
48Polyethers
4833Polyethers containing oxyethylene units
C08G 18/61
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
61Polysiloxanes
C08G 18/672
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
67Unsaturated compounds having active hydrogen
671Unsaturated compounds having only one group containing active hydrogen
672Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
Applicants
  • 株式会社ブリヂストン BRIDGESTONE CORPORATION [JP]/[JP] (AllExceptUS)
  • 石原 健延 ISHIHARA, Takenobu [JP]/[JP] (UsOnly)
Inventors
  • 石原 健延 ISHIHARA, Takenobu
Agents
  • 杉村 憲司 SUGIMURA, Kenji
Priority Data
2011-15838819.07.2011JP
Publication Language Japanese (JA)
Filing Language Japanese (JA)
Designated States
Title
(EN) LIGHT-CURING RESIN COMPOSITION, AND PLUMBING MEMBER AND FUNCTIONAL PANEL USING SAME
(FR) COMPOSITION DE RÉSINE POLYMÉRISABLE SOUS L'EFFET DE LA LUMIÈRE ET ÉLÉMENT DE TUYAUTERIE ET PANNEAU FONCTIONNEL L'UTILISANT
(JA) 光硬化性樹脂組成物、並びに、それを用いた水周り部材及び機能性パネル
Abstract
(EN)
Provided is a light-curing resin composition that exhibits improved characteristics such as slipperiness. This light-curing resin composition contains the following: a (A) dimethyl silicone (meth)acrylate oligomer obtained by reacting (a) a silicone polyol represented by general formula (1), (b) isocyanate, and a (c) (meth)acrylate monomer that has a terminal functional group that can react with isocyanate; a (B) photopolymerizable oligomer and/or (C) photopolymerizable monomer that can copolymerize with the aforementioned (A) dimethyl silicone (meth)acrylate oligomer; a (D) fluorine-containing compound; and a (E) photopolymerization initiator. In general formula (1), n represents an integer selected discretionarily so as to bring the number-average molecular weight of the (A) dimethyl silicone (meth)acrylate oligomer to between 700 and 40,000, inclusive; and R represents a C1-30 alkylene group or a C1-30 functional group having an ether bond.
(FR)
La présente invention concerne une composition de résine polymérisable sous l'effet de la lumière et présentant des caractéristiques améliorées, notamment en termes de glissance. Ladite composition de résine polymérisable sous l'effet de la lumière contient : (A) un oligomère de (méth)acrylate de silicone diméthylique résultant de la réaction (a) d'un silicone polyol représenté par la formule générale (1), (b) d'un isocyanate et (c) d'un monomère de (méth)acrylate comportant un groupe fonctionnel terminal capable de réagir avec l'isocyanate ; (B) un oligomère photopolymérisable et/ou (C) un monomère photopolymérisable pouvant faire l'objet d'une copolymérisation avec l'oligomère de (méth)acrylate de silicone diméthylique (A) susmentionné ; (D) un composé contenant du fluor ; et (E) un initiateur de photopolymérisation. Dans la formule générale (1), n représente un nombre entier choisi librement de façon à ce que la masse moléculaire moyenne en nombre de l'oligomère de (méth)acrylate de silicone diméthylique se situe entre 700 et 40 000, bornes incluses ; et R représente un groupe alkylène en C1 à C30 ou un groupe fonctionnel en C1 à C30 comportant une liaison éther.
(JA)
 滑り性等の性能を向上させることが可能な光硬化性樹脂組成物等を提供する。本発明の光硬化性樹脂組成物は、(A)(a)下記一般式(1)で表されるシリコーンポリオールと、(b)イソシアネートと、(c)末端にイソシアネートと反応可能な官能基を有する(メタ)アクリレートモノマーと、を反応させて得られるジメチルシリコーン(メタ)アクリレートオリゴマー、前記(A)ジメチルシリコーン(メタ)アクリレートオリゴマーと共重合可能な、(B)光重合性オリゴマー及び/又は(C)光重合性モノマー、(D)フッ素含有化合物、並びに、(E)光重合開始剤を含有する。但し、前記一般式(1)中、nは、前記(A)ジメチルシリコーン(メタ)アタリレートオリゴマーの数平均分子量が700~40000となるように任意に選択される整数を表し、Rは、総炭素数1~30のアルキレン基、又は、エーテル結合を有する総炭素数1~30の官能基を表す。
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