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1. WO2012174205 - ZEOLITIC CATALYTIC CONVERSION OF ALCOHOLS TO HYDROCARBONS

Publication Number WO/2012/174205
Publication Date 20.12.2012
International Application No. PCT/US2012/042399
International Filing Date 14.06.2012
IPC
C07C 1/20 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
1Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
20starting from organic compounds containing only oxygen atoms as hetero atoms
C10G 3/00 2006.1
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
3Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
B01J 29/46 2006.1
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29Catalysts comprising molecular sieves
04having base-exchange properties, e.g. crystalline zeolites, pillared clays
06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
40of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
42containing iron group metals, noble metals or copper
46Iron group metals or copper
B01J 29/48 2006.1
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29Catalysts comprising molecular sieves
04having base-exchange properties, e.g. crystalline zeolites, pillared clays
06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
40of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
48containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
C12P 7/06 2006.1
CCHEMISTRY; METALLURGY
12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
7Preparation of oxygen-containing organic compounds
02containing a hydroxy group
04acyclic
06Ethanol, i.e. non-beverage
C12P 7/08 2006.1
CCHEMISTRY; METALLURGY
12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
PFERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
7Preparation of oxygen-containing organic compounds
02containing a hydroxy group
04acyclic
06Ethanol, i.e. non-beverage
08produced as by-product or from waste or cellulosic material substrate
CPC
B01J 2229/183
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2229Aspects of molecular sieve catalysts not covered by B01J29/00
10After treatment, characterised by the effect to be obtained
18to introduce other elements into or onto the molecular sieve itself
183in framework positions
B01J 2229/186
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2229Aspects of molecular sieve catalysts not covered by B01J29/00
10After treatment, characterised by the effect to be obtained
18to introduce other elements into or onto the molecular sieve itself
186not in framework positions
B01J 29/061
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29Catalysts comprising molecular sieves
04having base-exchange properties, e.g. crystalline zeolites
06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
061containing metallic elements added to the zeolite
B01J 29/072
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29Catalysts comprising molecular sieves
04having base-exchange properties, e.g. crystalline zeolites
06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
064containing iron group metals, noble metals or copper
072Iron group metals or copper
B01J 29/076
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29Catalysts comprising molecular sieves
04having base-exchange properties, e.g. crystalline zeolites
06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
076containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B01J 29/143
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29Catalysts comprising molecular sieves
04having base-exchange properties, e.g. crystalline zeolites
06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
08of the faujasite type, e.g. type X or Y
10containing iron group metals, noble metals or copper
14Iron group metals or copper
143X-type faujasite
Applicants
  • UT-BATTELLE, LLC [US]/[US] (AllExceptUS)
  • NARULA, Chaitanya, K. [US]/[US] (UsOnly)
  • DAVISON, Brian, H. [US]/[US] (UsOnly)
  • KELLER, Martin [US]/[US] (UsOnly)
Inventors
  • NARULA, Chaitanya, K.
  • DAVISON, Brian, H.
  • KELLER, Martin
Agents
  • GROLZ, Edward, W.
Priority Data
61/497,25615.06.2011US
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) ZEOLITIC CATALYTIC CONVERSION OF ALCOHOLS TO HYDROCARBONS
(FR) CONVERSION CATALYTIQUE ZÉOLITIQUE D'ALCOOLS EN HYDROCARBURES
Abstract
(EN) A method for converting an alcohol to a hydrocarbon, the method comprising contacting said alcohol with a metal-loaded zeolite catalyst at a temperature of at least 100°C and up to 550°C, wherein said alcohol can be produced by a fermentation process, said metal is a positively-charged metal ion, and said metal-loaded zeolite catalyst is catalytically active for converting said alcohol to said hydrocarbon.
(FR) La présente invention concerne un procédé de conversion d'un alcool en hydrocarbure, le procédé comprenant la mise en contact dudit alcool avec un catalyseur zéolite chargé en métal à une température d'au moins 100°C et allant jusqu'à 550°C, ledit alcool pouvant être produit par le biais d'un processus de fermentation, ledit métal étant un ion métallique chargé positivement, et ledit catalyseur zéolite chargé en métal étant activé de manière catalytique dans le but de convertir ledit alcool en ledit hydrocarbure.
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