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1. (WO2012165435) FLUORINE-CONTAINING POLYMERIZABLE MONOMER AND POLYMER COMPOUND USING SAME
Latest bibliographic data on file with the International Bureau

Pub. No.: WO/2012/165435 International Application No.: PCT/JP2012/063781
Publication Date: 06.12.2012 International Filing Date: 29.05.2012
IPC:
C08G 63/193 (2006.01) ,C07C 39/367 (2006.01) ,C07C 43/295 (2006.01) ,C08L 63/00 (2006.01) ,C08L 67/03 (2006.01)
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
63
Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
02
Polyesters derived from hydroxy carboxylic acids or from polycarboxylic acids and polyhydroxy compounds
12
derived from polycarboxylic acids and polyhydroxy compounds
16
Dicarboxylic acids and dihydroxy compounds
18
the acids or hydroxy compounds containing carbocyclic rings
19
Hydroxy compounds containing aromatic rings
193
containing two or more aromatic rings
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
39
Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
24
Halogenated derivatives
367
polycyclic non-condensed, containing only six-membered aromatic rings, e.g. halogenated poly-(hydroxy-phenyl)alkanes
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
43
Ethers; Compounds having groups, groups or groups
02
Ethers
257
having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
295
containing hydroxy or O-metal groups
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
63
Compositions of epoxy resins; Compositions of derivatives of epoxy resins
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
67
Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
02
Polyesters derived from dicarboxylic acids and dihydroxy compounds
03
the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings
Applicants:
セントラル硝子株式会社 CENTRAL GLASS COMPANY, LIMITED [JP/JP]; 山口県宇部市大字沖宇部5253番地 5253, Oaza Okiube, Ube-shi, Yamaguchi 7550001, JP (AllExceptUS)
中辻 惇也 NAKATSUJI, Junya; null (UsOnly)
松浦 誠 MATSUURA, Makoto; null (UsOnly)
山中 一広 YAMANAKA, Kazuhiro; null (UsOnly)
Inventors:
中辻 惇也 NAKATSUJI, Junya; null
松浦 誠 MATSUURA, Makoto; null
山中 一広 YAMANAKA, Kazuhiro; null
Agent:
小林 博通 KOBAYASHI, Hiromichi; 東京都中央区明石町1番29号 掖済会ビル SHIGA内外国特許事務所内 c/o Shiga Patent Office, Ekisaikai Bldg., 1-29, Akashi-cho, Chuo-ku, Tokyo 1040044, JP
Priority Data:
2011-12103030.05.2011JP
2012-11843224.05.2012JP
Title (EN) FLUORINE-CONTAINING POLYMERIZABLE MONOMER AND POLYMER COMPOUND USING SAME
(FR) MONOMÈRE POLYMÉRISABLE CONTENANT DU FLUOR ET COMPOSÉ POLYMÈRE L'UTILISANT
(JA) 含フッ素重合性単量体およびそれを用いた高分子化合物
Abstract:
(EN) By means of the present invention, a fluorine-containing polymerizable monomer represented by general formula (1) and a polymer compound that uses the same are obtained. In formula (1), A is a single bond, oxygen atom, sulfur atom, SO2, CH2, CO, C(CH3)2, C(CH3)(CH2CH3), C(CF3)2,C(CH)3)(C6H6), CH2-C6H6-CH2, or phenyl, biphenyl, naphthalene, cyclohexene, or fluorolene from which two hydrogen atoms have been withdrawn; a and b are each independently an integer between 0 and 2; and 1 ≤ a + b ≤ 4. The resulting fluorine-containing polymer compound has the low water absorptivity of a fluorine compound, as well as adequate hydrophilicity and high transparency.
(FR) La présente invention concerne un monomère polymérisable contenant du fluor de formule générale (1) et un composé polymère l'utilisant. Dans la formule (1), A représente une simple liaison, un atome d'oxygène, un atome de soufre, SO2, CH2, CO, C(CH3)2, C(CH3)(CH2CH3), C(CF3)2, C(CH3)(C6H6), CH2-C6H6-CH2, ou un radical phényle, biphényle, naphtalène, cyclohexène, ou fluorolène dont deux atomes d'hydrogène ont été retirés; a et b représentent, indépendamment l'un de l'autre, un nombre entier entre 0 et 2; et 1 ≤ a + b ≤ 4. Le composé polymère contenant du fluor résultant présente la faible capacité d'absorption d'eau d'un composé fluoré, ainsi qu'une hydrophilicité adaptée et une grande transparence.
(JA)  本発明によれば、一般式(1)で表される含フッ素重合性単量体、およびそれを用いた高分子化合物が得られる。式(1)中、Aは単結合、酸素原子、硫黄原子、SO2、CH2、CO、C(CH32、C(CH3)(CH2CH3)、C(CF32、C(CH3)(C66)、CH2―C66―CH2、またはフェニル、ビフェニル、ナフタレン、シクロヘキセンもしくはフルオレンから水素原子が2個離脱したものを表わし、aとbはそれぞれ独立に0~2の整数であり、1≦a+b≦4である。 得られた含フッ素高分子化合物は、フッ素化合物が有する低吸水性に加え、適度な親水性および高い透明性を有する。
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, KE, KG, KM, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)
Also published as:
US20140100342KR1020140015586CN103562261