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1. WO2012057114 - CONDUCTIVE ANILINE POLYMER, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING CONDUCTIVE FILM

Publication Number WO/2012/057114
Publication Date 03.05.2012
International Application No. PCT/JP2011/074510
International Filing Date 25.10.2011
IPC
C08G 73/00 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
73Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen or carbon, not provided for in groups C08G12/-C08G71/238
C08J 5/18 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H142
5Manufacture of articles or shaped materials containing macromolecular substances
18Manufacture of films or sheets
CPC
B05D 5/12
BPERFORMING OPERATIONS; TRANSPORTING
05SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
DPROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
5Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
12to obtain a coating with specific electrical properties
C08G 73/0266
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
73Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
02Polyamines
026Wholly aromatic polyamines
0266Polyanilines or derivatives thereof
C08L 79/02
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
79Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
02Polyamines
C09D 179/02
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
179Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
02Polyamines
C09D 5/24
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
5Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced
24Electrically-conducting paints
H01B 1/128
HELECTRICITY
01BASIC ELECTRIC ELEMENTS
BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
1Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
06mainly consisting of other non-metallic substances
12organic substances
124Intrinsically conductive polymers
128comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
Applicants
  • 三菱レイヨン株式会社 Mitsubishi Rayon Co., Ltd. [JP]/[JP] (AllExceptUS)
  • 山田 耕平 YAMADA Kohei [JP]/[JP] (UsOnly)
  • 堀内 康司 HORIUCHI Yasushi [JP]/[JP] (UsOnly)
  • 蜂谷 有希子 HACHIYA Yukiko [JP]/[JP] (UsOnly)
  • 鵜澤 正志 UZAWA Masashi [JP]/[JP] (UsOnly)
  • 酒井 隆宏 SAKAI Takahiro [JP]/[JP] (UsOnly)
  • 高木 珠衣 TAKAGI Tamae [JP]/[JP] (UsOnly)
Inventors
  • 山田 耕平 YAMADA Kohei
  • 堀内 康司 HORIUCHI Yasushi
  • 蜂谷 有希子 HACHIYA Yukiko
  • 鵜澤 正志 UZAWA Masashi
  • 酒井 隆宏 SAKAI Takahiro
  • 高木 珠衣 TAKAGI Tamae
Agents
  • 志賀 正武 SHIGA Masatake
Priority Data
2010-24003926.10.2010JP
2011-00684917.01.2011JP
2011-03205317.02.2011JP
2011-07151729.03.2011JP
2011-08357905.04.2011JP
Publication Language Japanese (JA)
Filing Language Japanese (JA)
Designated States
Title
(EN) CONDUCTIVE ANILINE POLYMER, METHOD FOR PRODUCING SAME, AND METHOD FOR PRODUCING CONDUCTIVE FILM
(FR) POLYMÈRE D'ANILINE CONDUCTEUR, PROCÉDÉ DE PRODUCTION DUDIT POLYMÈRE ET PROCÉDÉ DE PRODUCTION DU FILM CONDUCTEUR
(JA) 導電性アニリン系ポリマーおよびその製造方法、導電性フィルムの製造方法
Abstract
(EN)
This conductive aniline polymer has a unit represented by formula (1). When the molecular weight distribution of this conductive aniline polymer is determined by gel permeation chromatography and the retention time is converted into a molecular weight (M) in terms of sodium polystyrene sulfonate, the area ratio of the area (X) of a region where the molecular weight (M) is 15,000 Da or more relative to the area (Y) of a region where the molecular weight (M) is less than 15,000 Da, namely X/Y is 1.20 or more. A method for producing this conductive aniline polymer comprises: a polymerization step (Z1) wherein a specific aniline derivative (A) is polymerized in a solution, which contains a basic compound (B), a solvent (C) and an oxidizing agent (D), at a liquid temperature of less than 25˚C; or a polymerization step (Z2) wherein a specific aniline derivative (A) and an oxidizing agent (D) are added into a liquid, wherein a conductive aniline polymer (P-1) having a unit represented by formula (1) is dissolved or dispersed in a solvent (C), and polymerized therein.
(FR)
L'invention concerne un polymère d'aniline conducteur qui a une unité représentée par la formule (1). Quand la distribution du poids moléculaire de ce polymère d'aniline conducteur est déterminée par chromatographie par perméation du gel et que le temps de rétention est converti en un poids moléculaire (M) en termes de polystyrènesulfonate de sodium, le rapport de surface de la surface (X) d'une région où le poids moléculaire (M) est de 15 000 Da ou plus par rapport à la surface (Y) d'une région où le poids moléculaire (M) est inférieur à 15 000 Da, à savoir X/Y, est de 1,20 ou plus. Un procédé de production de ce polymère d'aniline conducteur comprend : une étape de polymérisation (Z1) où un dérivé d'aniline spécifique (A) est polymérisé dans une solution, qui contient un composé basique (B), un solvant (C) et un agent oxydant (D), à une température du liquide de moins de 25˚C ; ou une étape de polymérisation (Z2) où un dérivé d'aniline spécifique (A) et un agent oxydant (D) sont ajoutés dans un liquide, où un polymère d'aniline conducteur (P-1) ayant une unité représentée par la formule (1) est dissous ou dispersé dans un solvant (C), et polymérisé dedans.
(JA)
 本発明の導電性アニリン系ポリマーは、下記式(1)で表される単位を有し、ゲル浸透クロマトグラフィーにより分子量分布を測定し、保持時間をポリスチレンスルホン酸ナトリウム換算の分子量(M)に変換し、この分子量(M)において、15000Da以上の領域の面積(X)と15000Da未満の領域の面積(Y)との面積比(X/Y)が1.20以上である。また、本発明の導電性アニリン系ポリマーの製造方法は、特定のアニリン誘導体(A)を、塩基性化合物(B)と溶剤(C)と酸化剤(D)とを含む溶液中、液温25℃未満で重合する重合工程(Z1)、または、下記式(1)で表される単位を有する導電性アニリン系ポリマー(P-1)が溶剤(C)に溶解あるいは分散した液中に、特定のアニリン誘導体(A)と酸化剤(D)とを添加して重合する重合工程(Z2)を有する。
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