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1. WO2012056166 - PROCESS FOR OBTAINING ACROLEIN BY CATALYTIC DEHYDRATION OF GLYCEROL OR GLYCERIN

Publication Number WO/2012/056166
Publication Date 03.05.2012
International Application No. PCT/FR2011/052492
International Filing Date 26.10.2011
IPC
C07C 45/52 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
45Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
51by pyrolysis, rearrangement or decomposition
52by dehydration and rearrangement involving two hydroxy groups in the same molecule
C07C 47/22 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
47Compounds having -CHO groups
20Unsaturated compounds having -CHO groups bound to acyclic carbon atoms
21with only carbon-to-carbon double bonds as unsaturation
22Acrylaldehyde; Methacrylaldehyde
C07C 319/18 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
18by addition of thiols to unsaturated compounds
C07C 319/20 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
20by reactions not involving the formation of sulfide groups
C07C 323/22 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
323Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
22containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
C07C 323/52 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
323Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
50containing thio groups and carboxyl groups bound to the same carbon skeleton
51having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
52the carbon skeleton being acyclic and saturated
CPC
B01J 23/30
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
16of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
24Chromium, molybdenum or tungsten
30Tungsten
C07C 319/14
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
C07C 319/18
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
18by addition of thiols to unsaturated compounds
C07C 319/20
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
20by reactions not involving the formation of sulfide groups
C07C 323/22
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
323Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
22containing thio groups and doubly-bound oxygen atoms bound to the same carbon skeleton
C07C 323/52
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
323Thiols, sulfides, hydropolysulfides or polysulfides substituted by halogen, oxygen or nitrogen atoms, or by sulfur atoms not being part of thio groups
50containing thio groups and carboxyl groups bound to the same carbon skeleton
51having the sulfur atoms of the thio groups bound to acyclic carbon atoms of the carbon skeleton
52the carbon skeleton being acyclic and saturated
Applicants
  • ADISSEO FRANCE S.A.S. [FR]/[FR] (AllExceptUS)
  • ECOLE CENTRALE DE LILLE [FR]/[FR] (AllExceptUS)
  • PARIENTE, Stéphane [FR]/[FR] (UsOnly)
  • BELLIERE-BACA, Virginie [FR]/[FR] (UsOnly)
  • PAUL, Sébastien [FR]/[FR] (UsOnly)
  • FATAH, Nouria [FR]/[FR] (UsOnly)
Inventors
  • PARIENTE, Stéphane
  • BELLIERE-BACA, Virginie
  • PAUL, Sébastien
  • FATAH, Nouria
Agents
  • CABINET GERMAIN & MAUREAU
Priority Data
10/5876726.10.2010FR
Publication Language French (FR)
Filing Language French (FR)
Designated States
Title
(EN) PROCESS FOR OBTAINING ACROLEIN BY CATALYTIC DEHYDRATION OF GLYCEROL OR GLYCERIN
(FR) PROCÉDÉ D'OBTENTION D'ACROLÉINE PAR DÉSHYDRATATION CATALYTIQUE DE GLYCÉROL OU DE GLYCÉRINE
Abstract
(EN)
A continuous process for obtaining acrolein by catalytic dehydration of glycerol or glycerin, in the presence of an acid catalyst, wherein said process comprises the concomitant regeneration of said catalyst and is carried out in a fluidized bed reactor, said reactor comprising two zones, a first zone, or lower zone, termed catalyst regeneration zone, in which a fluidization gas comprising oxygen is introduced, and a second zone, or upper zone, termed reaction zone, in which the glycerol or glycerin is introduced and converted into acrolein.
(FR)
Un procédé continu d 'obtention d'acroléine par déshydratation catalytique de glycérol ou de glycérine, en présence d'un catalyseur acide, ledit procédé comprenant la régénération concomitante dudit catalyseur et étant réalisé dans un réacteur à lit fluidisé, ledit réacteur comprenant deux zones, une première zone, ou zone inférieure, dite de régénération du catalyseur dans laquelle un gaz de fluidisation comprenant de l'oxygène est introduit et une seconde zone, ou zone supérieure, dite de réaction dans lequel le glycérol ou la glycérine est introduit et converti en acroléine.
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