5. WO2012026194 - METAL OXIDE NANOPARTICLE STRUCTURE AND PRODUCTION METHOD FOR SAME

Publication Number WO/2012/026194

Publication Date 01.03.2012

International Application No. PCT/JP2011/064173

International Filing Date 21.06.2011

Chapter 2 Demand Filed 20.04.2012

IPC

C01B 13/36 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
B	NON-METALLIC ELEMENTS; COMPOUNDS THEREOF
13	Oxygen; Ozone; Oxides or hydroxides in general
14	Methods for preparing oxides or hydroxides in general
36	by precipitation reactions in solutions

C01F 17/00 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
F	COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE EARTH METALS
17	Compounds of rare earth metals

C01G 3/02 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
3	Compounds of copper
02	Oxides; Hydroxides

C01G 9/02 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
9	Compounds of zinc
02	Oxides; Hydroxides

C01G 23/053 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
23	Compounds of titanium
04	Oxides; Hydroxides
047	Titanium dioxide
053	Producing by wet processes, e.g. hydrolysing titanium salts

C01G 49/08 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
49	Compounds of iron
02	Oxides; Hydroxides
08	Ferroso-ferric oxide

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C01B 13/36 2006.1

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01	INORGANIC CHEMISTRY
B	NON-METALLIC ELEMENTS; COMPOUNDS THEREOF
13	Oxygen; Ozone; Oxides or hydroxides in general
14	Methods for preparing oxides or hydroxides in general
36	by precipitation reactions in solutions

C01F 17/00 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
F	COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE EARTH METALS
17	Compounds of rare earth metals

C01G 3/02 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
3	Compounds of copper
02	Oxides; Hydroxides

C01G 9/02 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
9	Compounds of zinc
02	Oxides; Hydroxides

C01G 23/053 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
23	Compounds of titanium
04	Oxides; Hydroxides
047	Titanium dioxide
053	Producing by wet processes, e.g. hydrolysing titanium salts

C01G 49/08 2006.1

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F94
49	Compounds of iron
02	Oxides; Hydroxides
08	Ferroso-ferric oxide

C01G 51/04 2006.1

C	CHEMISTRY; METALLURGY
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51	Compounds of cobalt
04	Oxides

C01G 53/04 2006.1

C	CHEMISTRY; METALLURGY
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53	Compounds of nickel
04	Oxides

C12P 1/00 2006.1

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1	Preparation of compounds or compositions, not provided for in groups C12P3/-C12P39/121; General processes for the preparation of compounds or compositions by using microorganisms or enzymes

A61B 5/055 2006.1

A	HUMAN NECESSITIES
61	MEDICAL OR VETERINARY SCIENCE; HYGIENE
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B01J 21/063

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21	Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
06	Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
063	Titanium; Oxides or hydroxides thereof

B01J 2235/00

B01J 2235/15

B01J 2235/30

B01J 23/06

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
06	of zinc, cadmium or mercury

B01J 23/10

B	PERFORMING OPERATIONS; TRANSPORTING
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23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
10	of rare earths

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B01J 21/063

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J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21	Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
06	Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
063	Titanium; Oxides or hydroxides thereof

B01J 2235/00

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B01J 2235/30

B01J 23/06

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
06	of zinc, cadmium or mercury

B01J 23/10

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
10	of rare earths

B01J 23/72

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70	of the iron group metals or copper
72	Copper

B01J 23/745

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70	of the iron group metals or copper
74	Iron group metals
745	Iron

B01J 23/75

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01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70	of the iron group metals or copper
74	Iron group metals
75	Cobalt

B01J 23/755

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23	Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70	of the iron group metals or copper
74	Iron group metals
755	Nickel

B01J 35/39

B01J 35/615

B01J 35/70

B01J 37/03

B	PERFORMING OPERATIONS; TRANSPORTING
01	PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J	CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37	Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
02	Impregnation, coating or precipitation
03	Precipitation; Co-precipitation

C01B 13/36

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
B	NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; ; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
13	Oxygen; Ozone; Oxides or hydroxides in general
14	Methods for preparing oxides or hydroxides in general
36	by precipitation reactions in ; aqueous; solutions

C01F 17/224

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
F	COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
17	Compounds of rare earth metals
20	Compounds containing only rare earth metals as the metal element
206	oxide or hydroxide being the only anion
224	Oxides or hydroxides of lanthanides

C01G 23/053

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
23	Compounds of titanium
04	Oxides; Hydroxides
047	Titanium dioxide
053	Producing by wet processes, e.g. hydrolysing titanium salts

C01G 3/02

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
3	Compounds of copper
02	Oxides; Hydroxides

C01G 49/08

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
49	Compounds of iron
02	Oxides; Hydroxides
08	Ferroso-ferric oxide (Fe3O4)

C01G 51/04

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
51	Compounds of cobalt
04	Oxides; Hydroxides

C01G 53/04

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
53	Compounds of nickel
04	Oxides; Hydroxides

C01G 9/02

C	CHEMISTRY; METALLURGY
01	INORGANIC CHEMISTRY
G	COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
9	Compounds of zinc
02	Oxides; Hydroxides

C01P 2002/72

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01	INORGANIC CHEMISTRY
P	INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
2002	Crystal-structural characteristics
70	defined by measured X-ray, neutron or electron diffraction data
72	by d-values or two theta-values, e.g. as X-ray diagram

C01P 2004/03

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01	depicted by an image
03	obtained by SEM

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01	depicted by an image
04	obtained by TEM, STEM, STM or AFM

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2006	Physical properties of inorganic compounds
12	Surface area

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3	Preparation of elements or inorganic compounds except carbon dioxide

C12Y 305/01005

C	CHEMISTRY; METALLURGY
12	BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
Y	ENZYMES
305	Hydrolases acting on carbon-nitrogen bonds, other than peptide bonds (3.5)
01	in linear amides (3.5.1)
01005	Urease (3.5.1.5)

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Applicants

• 国立大学法人　徳島大学 THE UNIVERSITY OF TOKUSHIMA [JP]/[JP](AllExceptUS)
• 林　幸壱朗 HAYASHI Koichiro [JP]/[JP](UsOnly)

Inventors

• 林　幸壱朗 HAYASHI Koichiro

Agents

• 石井　久夫 ISHII Hisao

Priority Data

2010-187967

25.08.2010

JP

Publication Language Japanese (ja)

Filing Language Japanese (ja)

Designated States

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AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PE, PG, PH, PL, PT, RO, RS, RU, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, SD, SL, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, ML, MR, NE, SN, TD, TG)

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Title

(EN) METAL OXIDE NANOPARTICLE STRUCTURE AND PRODUCTION METHOD FOR SAME

(FR) STRUCTURE DE NANOPARTICULES EN OXYDE MÉTALLIQUE ET LEUR PROCÉDÉ DE PRODUCTION

(JA) 金属酸化物ナノ粒子構造体およびその製造方法

Abstract

(EN) [Problem] To provide a two-dimensional or three-dimensional metal oxide structure using biomimetic processing. [Solution] A jack bean urease (JBU) derived from jack beans is used as a urease and, by the template effect thereof, urea is degraded and a two-dimensional or three-dimensional structure comprising metal oxide nanoparticles is manufactured. By means of this invention, the metal oxide is formed in a sheet and exhibits superparamagnetism, and a flower-like hierarchical structure exhibits a desirable strong magnetism and usefulness as an MRI contrast media. A titanium oxide forms a rutile-type titanium oxide that exhibits high photocatalytic activity at a low temperature of 37°C.

(FR) [Problème] Obtenir une structure d'oxyde métallique bi- ou tridimensionnelle par un traitement biomimétique. [Solution] Une uréase de haricot jacquier (JBU) dérivée de haricots jacquiers est utilisée à titre d'uréase et, par son effet de matrice, l'urée est dégradée et une structure bi- ou tridimensionnelle comprenant des nanoparticules d'oxyde métallique est obtenue. Grâce à cette invention, l'oxyde métallique est formé sous la forme d'une feuille et manifeste un supraparamagnétisme, et une structure hiérarchique en forme de fleur manifeste le fort magnétisme recherché et s'avère utile en tant que milieu de contraste en IRM. Un oxyde de titane forme un oxyde de titane de type rutile qui manifeste une activité photocatalytique élevée à une basse température de 37°C.

(JA) 【課題】 生体模倣プロセスを用いて金属酸化物の二次元または三次元構造体を提供すること。 【解決手段】 本発明は、ウレアーゼとしてジャックビーンズ由来のタチナタマメウレアーゼ（ＪＢＵ）を用い、そのテンプレート効果により、尿素を分解させ、金属酸化物のナノ粒子からなる二次元または三次元構造物を製造する。本発明によれば、鉄系酸化物はシート状に形成されて超常磁性を示し、花型階層構造体は好ましい強磁性を示し、MRI造影剤として有用性を示す。チタン系酸化物は３７℃という低温で、高い光触媒活性を示すルチル型チタン酸化物が形成される。

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