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1. (WO2011134911) FUNGICIDE HYDROXIMOYL-TETRAZOLE DERIVATIVES
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CLAIMS

A compound of formula (I)


(I)

wherein

A represents a tetrazolyl group of formula (A1) or (A2):


(A1) (A2)

wherein Y represents a substituted or non-substituted C3-C8-cycloalkyl, a hydrogen atom, CR R2R3, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted C2-C8-alkenyl, or substituted or non-substituted C2-C8-alkynyl;

wherein

o R , R2 and R3 are independently selected in the list consisting of hydrogen, halogen, [d-C4]-alkyl, [Ci-C4]-haloalkyl, [C2-C4]-alkenyl, [C2-C4]-haloalkenyl, [C2-C4]-alkynyl, [C2-C4]-haloalkynyl, [C3-C5]-cycloalkyl, [C3-C5]-halocycloalkyl, [C C4]-alkoxy, [C C4]- alkoxy-[Ci-C4]-alkyl, [Ci-C4]-alkoxy-[Ci-C4]-alkoxy, [Ci-C4]-haloalkoxy, [Ci-C4]- haloalkoxy-[Ci-C4]-alkyl, [Ci-C6]-alkoxy-carbonyl, [CrC6]-alkoxy- carbonyl-[Ci-C4]- alkyl, tri(Ci-C8-alkyl)silyl and tri(C1-C8-alkyl)silyl-[C1-C4]-alkyl and cyano, or o R and R2 can form a 3- to 7-membered, saturated or unsaturated, carbo- or heterocycle;

o provided that if R and R2 both represent a hydrogen atom, R3 represents a halogen atom, [d-C4]-haloalkyl, [C2-C4]-alkenyl, [C2-C4]-haloalkenyl, [C2-C4]-alkynyl, [C2-C4]- haloalkynyl, [C3-C5]-cycloalkyl, [C3-C5]-halocycloalkyl, [Ci-C4]-alkoxy, [Ci-C4]-alkoxy- [Ci-C4]-alkyl, [Ci-C4]-alkoxy-[Ci-C4]-alkoxy, [Ci-C4]-haloalkoxy, [Ci-C4]-haloalkoxy-[Ci- C4]-alkyl, [Ci-C6]-alkoxy-carbonyl, [d-C6]-alkoxy- carbonyl-[Ci-C4]-alkyl, tri(Ci-C8- alkyl)silyl, tri(Ci-C8-alkyl)silyl-[Ci-C4]-alkyl or cyano;

• Het represents a pyridyl group of formula (Het1) or a thiazol l group of formula (Het2) ;


(Het1) (Het2)

wherein

o R represents a hydrogen atom or a halogen atom ;

o Z represents a hydrogen atom, an amino group, a halogen atom, a hydroxy group, substituted or non-substituted Ci-C8-alkyl, substituted or non-substituted C3-C8- cycloalkyl, a substituted or non-substituted C2-C8-alkenyl, substituted or non- substituted C2-C8-alkynyl, substituted or non-substituted Ci-C8-alkoxy, substituted or non-substituted Ci-C8-alkylamino, substituted or non-substituted C3-Ci0- cycloalkylamino, substituted or non-substituted C3-Ci0-cycloalkenylamino, substituted or non-substituted C5-Ci2-fused bicycloalkylamino, substituted or non-substituted C5- Ci2-fused bicycloalkenylamino, substituted or non-substituted di-Ci-C8-alkylamino, substituted or non-substituted phenylamino, substituted or non-substituted heterocyclylamino, or a group of formula QC(=U)NRa- wherein:

- Q represents a hydrogen atom, substituted or non-substituted Ci-C8-alkyl, substituted or non-substituted Ci-C8-cycloalkyl, a substituted or non-substituted C2-C8- alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted Ci-C8-alkoxy, substituted or non-substituted Ci-C8-alkylamino, substituted or non- substituted Ci-C8-alkylsulphenyl, substituted or non-substituted arylsulphenyl, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted C5-Ci2-fused bicycloalkyl, substituted or non-substituted C5-Ci2-fused bicycloalkenyl, or substituted or non-substituted C5-Ci2-benzofused carbocyclyl;

- U represents a oxygen atom or a sulphur atom and

- Ra represents a hydrogen atom, substituted or non-substituted Ci-C8-alkyl, substituted or non-substituted Ci-C8-cycloalkyl, a substituted or non-substituted C2-C8- alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted aryl, or substituted or non-substituted heterocyclyl;

• X independently represents a hydrogen atom, a halogen atom, substituted or non-substituted Ci-C8-alkyl, an Ci-C8-alkoxy group, a cyano group, a methanesulfonyl group, a nitro group, a Ci-C8-halogenoalkyl having 1 to 5 halogen atoms or an aryl group ;

• q represents 1 , 2, 3, 4 or 5;

as well as salts, N-oxides, metallic complexes and metalloidic complexes thereof.

2. A compound according to claim 1 wherein Y represents substituted or non-substituted C3-C8-cycloalkyl, CR R2R3, or substituted or non-substituted C2-C8-alkenyl.

3. A compound according to any one of claims 1 to 2 wherein R , R2 and R3 are independently selected in the list consisting of hydrogen, halogen, [Ci-C4]-alkyl, [Ci-C4]-haloalkyl, [d-C6]-alkoxy-carbonyl, [d-C6]-alkoxy- carbonyl-[Ci-C4]-alkyl, tri(Ci-C8-alkyl)silyl, tri(Ci-C8-alkyl)silyl-[Ci-C4]-alkyl and cyano; or R and R2 can form a 3- to 5-membered, saturated or unsaturated , carbo- and heterocycle;

4. A compound according to any one of claims 1 to 3 wherein R , R2 and R3 are independently selected in the list consisting of hydrogen, halogen, [CrC6]-alkoxy-carbonyl, and tri(Ci-C8-alkyl)silyl; or wherein R and R2 can form a cyclopropyl ring ;

5. A compound according to any one of claims 1 to 4 wherein X independently represents a hydrogen atom or a halogen atom .

6. A compound according to claim 5 wherein X represents a hydrogen atom.

7. A compound according to any one of claims 1 to 6 wherein q represents 1 or 2.

8. A compound according to any one of claims 1 to 7 wherein R represents a hydrogen atom.

9. A compound according to any one of claims 1 to 8 wherein Z represents an amino group, a halogen atom, a substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted Ci-C8-alkylamino, substituted or non-substituted C3-Ci0-cycloalkylamino, or a group of formula QC(=U)NRa- .

10. A compound according to any one of claims 1 to 9 wherein Q represents a hydrogen atom, substituted or non-substituted Ci-C8-alkyl, substituted or non-substituted Ci-C8-cycloalkyl, a substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted Ci-C8-alkoxy, substituted or non-substituted Ci-C8-alkylsulphenyl, substituted or non-substituted arylsulphenyl, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted C5-Ci2-fused bicycloalkyl, substituted or non-substituted C5-Ci2-fused bicycloalkenyl, or substituted or non-substituted C5-Ci2-benzofused carbocyclyl: Particularly substituted or non-substituted Ci-C8-alkyl, substituted or non-substituted Ci-C8-alkoxy, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, or substituted or non-substituted C5-Ci2-benzofused carbocyclyl.

1 1 . A compound according to any one of claims 1 to 10 wherein U represents an oxygen atom.

12. A compound according to any one of claims 1 to 1 1 wherein Ra represents a hydrogen atom or substituted or non-substituted Ci-C8-alkyl.

13. A compound of formula (II)1


wherein Y, X and q are as defined in any one of claims 1 to 12.

14. A fungicide composition comprising, as an active ingredient, an effective amount of a compound of formula (I) according to claims 1 to 12 and an agriculturally acceptable support, carrier or filler.

15. A method for controlling phytopathogenic fungi of crops, characterized in that an agronomically effective and substantially non-phytotoxic quantity of a compound according to claims 1 to 12 or a composition according to claim 14 is applied to the soil where plants grow or are capable of growing, to the leaves and/or the fruit of plants or to the seeds of plants.