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1. WO2010026962 - FLUORINE-CONTAINING ADAMANTANE DERIVATIVES, AND MANUFACTURING METHOD AND USES THEREFOR

Publication Number WO/2010/026962
Publication Date 11.03.2010
International Application No. PCT/JP2009/065257
International Filing Date 01.09.2009
IPC
C07C 43/13 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
43Ethers; Compounds having groups, groups or groups
02Ethers
03having all ether-oxygen atoms bound to acyclic carbon atoms
04Saturated ethers
13containing hydroxy or O-metal groups
C07C 41/03 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
41Preparation of ethers; Preparation of compounds having groups, groups or groups
01Preparation of ethers
02from oxiranes
03by reaction of an oxirane ring with a hydroxy group
C07C 41/16 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
41Preparation of ethers; Preparation of compounds having groups, groups or groups
01Preparation of ethers
16by reaction of esters of mineral or organic acids with hydroxy or O-metal groups
C07C 41/24 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
41Preparation of ethers; Preparation of compounds having groups, groups or groups
01Preparation of ethers
18by reactions not forming ether-oxygen bonds
24by elimination of halogen, e.g. elimination of HCl
C07C 43/196 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
43Ethers; Compounds having groups, groups or groups
02Ethers
18having an ether-oxygen atom bound to a carbon atom of a ring other than a six-membered aromatic ring
196containing hydroxy or O-metal groups
C07C 69/54 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
69Esters of carboxylic acids; Esters of carbonic or haloformic acids
52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
533Monocarboxylic acid esters having only one carbon-to-carbon double bond
54Acrylic acid esters; Methacrylic acid esters
CPC
C07C 2603/74
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2603Systems containing at least three condensed rings
56Ring systems containing bridged rings
58containing three rings
70containing only six-membered rings
74Adamantanes
C07C 43/137
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
43Ethers; Compounds having groups, groups or groups
02Ethers
03having all ether-oxygen atoms bound to acyclic carbon atoms
04Saturated ethers
13containing hydroxy or O-metal groups
137containing halogen
C07C 43/196
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
43Ethers; Compounds having groups, groups or groups
02Ethers
18having an ether-oxygen atom bound to a carbon atom of a ring other than a six-membered aromatic ring
196containing hydroxy or O-metal groups
C07C 69/54
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
69Esters of carboxylic acids; Esters of carbonic or haloformic acids
52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
533Monocarboxylic acid esters having only one carbon-to-carbon double bond
54Acrylic acid esters; Methacrylic acid esters
C07C 69/653
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
69Esters of carboxylic acids; Esters of carbonic or haloformic acids
62Halogen-containing esters
65of unsaturated acids
653Acrylic acid esters; Methacrylic acid esters; Haloacrylic acid esters; Halomethacrylic acid esters
C08F 20/24
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
20Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
10Esters
22Esters containing halogen
24containing perhaloalkyl radicals
Applicants
  • 出光興産株式会社 IDEMITSU KOSAN CO., LTD. [JP]/[JP] (AllExceptUS)
  • 上野山 義崇 UENOYAMA, Yoshitaka [JP]/[JP] (UsOnly)
  • 伊藤 克樹 ITO, Katsuki [JP]/[JP] (UsOnly)
  • 大野 英俊 ONO, Hidetoshi [JP]/[JP] (UsOnly)
Inventors
  • 上野山 義崇 UENOYAMA, Yoshitaka
  • 伊藤 克樹 ITO, Katsuki
  • 大野 英俊 ONO, Hidetoshi
Agents
  • 大谷 保 OHTANI, Tamotsu
Priority Data
2008-22950508.09.2008JP
Publication Language Japanese (ja)
Filing Language Japanese (JA)
Designated States
Title
(EN) FLUORINE-CONTAINING ADAMANTANE DERIVATIVES, AND MANUFACTURING METHOD AND USES THEREFOR
(FR) DÉRIVÉS D’ADAMANTANE CONTENANT DU FLUOR, LEUR PROCÉDÉ DE FABRICATION ET LEURS UTILISATIONS
(JA) 含フッ素アダマンタン誘導体、その製造方法及びその用途
Abstract
(EN) Provided are fluorine-containing adamantane derivatives represented by general formula (I) that provide cured products, which are suitable as electronic and optical materials and have superior heat resistance, mar resistance, low refractive index and mechanical properties, and manufacturing method and uses therefor. [In the formula, A represents a single bond or 1-10 carbon n-valent hydrocarbon group that may be substituted. X is a specific polymerizable group and multiple Xs can be the same or different. Y represents an oxygen atom or divalent hydrocarbon group that may comprise an oxygen atom. Z represents an adamantyl group wherein 1 or more hydrogen atoms have been substituted with fluorine atoms. n is an integer 1-4.]
(JA)  電子材料や光学材料に好適な、耐熱性、耐擦傷性、低屈折率及び機械物性に優れた硬化物を与える、下記一般式(I)で表される含フッ素アダマンタン誘導体、その製造方法及びその用途である。[式中、Aは単結合又は置換してもよい炭素数1~10のn価の炭化水素基を示す。Xは特定の重合性基であり、複数のXは同一であっても異なっていてもよい。Yは酸素原子又は酸素原子を含んでもよい二価の炭化水素基を示す。Zは1つ以上の水素原子がフッ素原子で置換されたアダマンチル基を示す。nは1~4の整数である。]
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