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1. (WO2007007992) TRANSITION METAL COMPLEXES, CATALYST COMPOSITIONS CONTAINING THE SAME, AND OLEFIN POLYMERIZATION USING THE CATALYST COMPOSITIONS
Latest bibliographic data on file with the International Bureau

Pub. No.: WO/2007/007992 International Application No.: PCT/KR2006/002666
Publication Date: 18.01.2007 International Filing Date: 07.07.2006
IPC:
C08F 4/64 (2006.01)
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
42
Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44
selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
60
together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
62
Refractory metals or compounds thereof
64
Titanium, zirconium, hafnium, or compounds thereof
Applicants:
LG CHEM, LTD. [KR/KR]; 20 Yoido-dong, Youngdungpo-gu Seoul 150-721, KR (AllExceptUS)
LEE, Choong-Hoon [KR/KR]; KR (UsOnly)
LEE, Eunjung [KR/KR]; KR (UsOnly)
JUNG, Seungwhan [KR/KR]; KR (UsOnly)
HA, Jong-Joo [KR/KR]; KR (UsOnly)
SEO, Beomdoo [KR/KR]; KR (UsOnly)
LEE, Bun Yeoul [KR/KR]; KR (UsOnly)
JOUNG, Ui-Gab [KR/KR]; KR (UsOnly)
JOE, Dae-June [KR/KR]; KR (UsOnly)
Inventors:
LEE, Choong-Hoon; KR
LEE, Eunjung; KR
JUNG, Seungwhan; KR
HA, Jong-Joo; KR
SEO, Beomdoo; KR
LEE, Bun Yeoul; KR
JOUNG, Ui-Gab; KR
JOE, Dae-June; KR
Agent:
Y.P.LEE, MOCK & PARTNERS; 1575-1 Seocho-dong, Seocho-gu Seoul 137-875, KR
Priority Data:
10-2005-006182008.07.2005KR
Title (EN) TRANSITION METAL COMPLEXES, CATALYST COMPOSITIONS CONTAINING THE SAME, AND OLEFIN POLYMERIZATION USING THE CATALYST COMPOSITIONS
(FR) COMPLEXES DE MÉTAUX DE TRANSITION, COMPOSITIONS DE CATALYSEURS LES COMPRENANT ET POLYMÉRISATION D’OLÉFINES UTILISANT LES COMPOSITIONS DE CATALYSEURS
Abstract:
(EN) Provided are a novel transition metal complex where a monocyclopentadienyl ligand to which an amido or alcoxy group is introduced is coordinated, a method of synthesizing the same, and olefin polymerization using the transition metal complex . Compared to a conventional transition metal complex having a silicon bridge and an oxido ligand, the transition metal complex has a phenylene bridge, so that a monomer easily approaches the transition metal complex in terms of structure and a pentagon ring structure of the transition metal complex is stably maintained. The catalyst composition including the transition metal complex is used to synthesize a polyolefin copolymer having a very low density less than 0.910 g/cc.
(FR) La présente invention concerne un nouveau complexe de métal de transition où un ligand monocyclopentadiényle, dans lequel on introduit un groupe amido ou alcoxy, est coordonné, un procédé de synthèse de celui-ci et une polymérisation des oléfines qui utilise le complexe de métal de transition. Comparativement à un complexe de métal de transition traditionnel qui possède un pont silicium et un ligand oxydo, le complexe de métal de transition possède un pont phénylène, de sorte qu'un monomère approche facilement le complexe de métal de transition relativement à la structure, et une structure de noyau en forme de pentagone du complexe de métal de transition est maintenue stable. La composition de catalyseur qui comprend le complexe de métal de transition est utilisée pour synthétiser un copolymère de polyoléfine qui possède une très basse densité inférieure à 0,910 g/cc.
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Designated States: AE, AG, AL, AM, AT, AU, AZ, BA, BB, BG, BR, BW, BY, BZ, CA, CH, CN, CO, CR, CU, CZ, DE, DK, DM, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, KZ, LA, LC, LK, LR, LS, LT, LU, LV, LY, MA, MD, MG, MK, MN, MW, MX, MZ, NA, NG, NI, NO, NZ, OM, PG, PH, PL, PT, RO, RS, RU, SC, SD, SE, SG, SK, SL, SM, SY, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LS, MW, MZ, NA, SD, SL, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM)
European Patent Office (AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HU, IE, IS, IT, LT, LU, LV, MC, NL, PL, PT, RO, SE, SI, SK, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)
Also published as:
JP2009500403US20090209712CN101223195DE112006001798