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1. WO2006126680 - AQUEOUS RESIN COMPOSITION, WEATHER RESISTANCE IMPROVER FOR AQUEOUS COATING MATERIAL USING SAME, WEATHER RESISTANCE IMPROVER FOR THERMOPLASTIC RESIN, AND WEATHER RESISTANCE IMPROVER FOR SOLVENT BORNE COATING MATERIAL

Publication Number WO/2006/126680
Publication Date 30.11.2006
International Application No. PCT/JP2006/310569
International Filing Date 26.05.2006
IPC
C08L 33/14 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
33Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Compositions of derivatives of such polymers
04Homopolymers or copolymers of esters
14of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
C09D 5/02 2006.1
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
5Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
02Emulsion paints
C09D 7/12 2006.1
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
7Features of coating compositions, not provided for in group C09D5/88; Processes for incorporating ingredients in coating compositions
12Other additives
C09D 133/14 2006.1
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
133Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
04Homopolymers or copolymers of esters
14of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
CPC
C08F 2/26
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
12Polymerisation in non-solvents
16Aqueous medium
22Emulsion polymerisation
24with the aid of emulsifying agents
26anionic
C08F 220/18
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
12of monohydric alcohols or phenols
16of phenols or of alcohols containing two or more carbon atoms
18with acrylic or methacrylic acids
C08F 220/1804
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
12of monohydric alcohols or phenols
16of phenols or of alcohols containing two or more carbon atoms
18with acrylic or methacrylic acids
1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
C08F 220/34
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
34Esters containing nitrogen ; , e.g. N,N-dimethylaminoethyl (meth)acrylate
C08F 220/36
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
34Esters containing nitrogen ; , e.g. N,N-dimethylaminoethyl (meth)acrylate
36containing oxygen in addition to the carboxy oxygen ; , e.g. 2-N-morpholinoethyl (meth)acrylate or 2-isocyanatoethyl (meth)acrylate
C09D 5/024
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
5Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced
02Emulsion paints ; including aerosols
024characterised by the additives
Applicants
  • 三菱レイヨン株式会社 MITSUBISHI RAYON CO., LTD. [JP]/[JP] (AllExceptUS)
  • 椋田 貴寛 MUKUDA, Takahiro [JP]/[JP] (UsOnly)
  • 木浦 正明 KIURA, Masaaki [JP]/[JP] (UsOnly)
  • 田中 基巳 TANAKA, Motomi [JP]/[JP] (UsOnly)
Inventors
  • 椋田 貴寛 MUKUDA, Takahiro
  • 木浦 正明 KIURA, Masaaki
  • 田中 基巳 TANAKA, Motomi
Priority Data
2005-15410926.05.2005JP
2005-21483025.07.2005JP
2005-35792512.12.2005JP
2006-05480601.03.2006JP
2006-06144707.03.2006JP
2006-06149607.03.2006JP
Publication Language Japanese (ja)
Filing Language Japanese (JA)
Designated States
Title
(EN) AQUEOUS RESIN COMPOSITION, WEATHER RESISTANCE IMPROVER FOR AQUEOUS COATING MATERIAL USING SAME, WEATHER RESISTANCE IMPROVER FOR THERMOPLASTIC RESIN, AND WEATHER RESISTANCE IMPROVER FOR SOLVENT BORNE COATING MATERIAL
(FR) COMPOSITION AQUEUSE DE RÉSINE, AGENT AMÉLIORANT LA RÉSISTANCE AUX INTEMPÉRIES POUR UNE MATIÈRE AQUEUSE DE REVÊTEMENT UTILISANT CELLE-CI, AGENT AMÉLIORANT LA RÉSISTANCE AUX INTEMPÉRIES POUR UNE RÉSINE THERMOPLASTIQUE ET AGENT AMÉLIORANT LA RÉS
(JA) 水性樹脂組成物及びそれを用いた水性塗料用耐候性向上材、熱可塑性樹脂用耐候性向上材、溶剤系塗料用耐候性向上材
Abstract
(EN) Disclosed is an aqueous resin composition containing a copolymer (A) which is obtained by emulsion-polymerizing an unsaturated monomer composed of 0.5-50 parts by mass of a specific ethylenically unsaturated monomer (a) having a piperidyl group and 50-99.5 parts by mass of an ethylenically unsaturated monomer (b), which does not substantially include an ethylenically unsaturated monomer having a specific functional group in a molecule, (with the total of the components (a) and (b) being 100 parts by mass) in the coexistence of 0.1-10 parts by mass of an emulsifying agent. Also disclosed are a weather resistance improver for aqueous coating materials, weather resistance improver for thermoplastic resins and weather resistance improver for solvent borne coating materials respectively using such an aqueous resin composition.
(FR) L’invention concerne une composition aqueuse de résine contenant un copolymère (A) lequel est obtenu par polymérisation en émulsion d'un monomère insaturé composé de 0,5-50 parties en poids d'un monomère à insaturation éthylénique spécifique (a) ayant un groupe pipéridyle et de 50-99,5 parties en poids d'un monomère à insaturation éthylénique (b), lequel ne comprend pratiquement pas de monomère à insaturation éthylénique ayant un groupe fonctionnel spécifique dans sa molécule (le total des composants (a) et (b) étant de 100 parties en poids) en présence de 0,1-10 parties en poids d'un agent émulsifiant. L’invention concerne également un agent améliorant la résistance aux intempéries pour des matières aqueuses de revêtement, un agent améliorant la résistance aux intempéries pour des résines thermoplastiques et un agent améliorant la résistance aux intempéries pour des matières de revêtement à base de solvant utilisant chacun une telle composition aqueuse de résine.
(JA)  本願発明の要旨は、ピペリジル基を持つ特定のエチレン性不飽和単量体(a)0.5~50質量部と、分子内に特定の官能基を有するエチレン性不飽和単量体を実質的に含まないエチレン性不飽和単量体(b)50~99.5質量部[但し、成分(a)、(b)の合計は100質量部]からなる不飽和単量体を、乳化剤0.1~10質量部の共存下で乳化重合することで得られる共重合体(A)を含む水性樹脂組成物にある。  また、本発明の要旨は、前記水性樹脂組成物を用いた水性塗料用耐候性向上材、熱可塑性樹脂用耐候性向上材、溶剤系塗料用耐候性向上材にある。
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