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1. WO2006116279 - PERFLUOROAMIDATED AND HYDROLYZED MALEIC ANHYDRIDE COPOLYMERS

Publication Number WO/2006/116279
Publication Date 02.11.2006
International Application No. PCT/US2006/015426
International Filing Date 24.04.2006
Chapter 2 Demand Filed 09.02.2007
IPC
C08F 8/32 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
8Chemical modification by after-treatment
30Introducing nitrogen atoms or nitrogen-containing groups
32by reaction with amines
C08F 8/00 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
8Chemical modification by after-treatment
D06M 15/295 2006.1
DTEXTILES; PAPER
06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D0664
15Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials with macromolecular compounds; Such treatment combined with mechanical treatment
19with synthetic macromolecular compounds
21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
285of unsaturated carboxylic acid amides or imides
295containing fluorine
CPC
C08F 210/00
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
210Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
C08F 216/12
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
216Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical
12by an ether radical
C08F 220/00
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
C08F 220/06
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
04Acids; Metal salts or ammonium salts thereof
06Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
C08F 8/00
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
8Chemical modification by after-treatment
D06M 15/295
DTEXTILES; PAPER
06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
15Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
19with synthetic macromolecular compounds
21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
285of unsaturated carboxylic acid amides or imides
295containing fluorine
Applicants
  • E.I. DU PONT DE NEMOURS AND COMPANY [US]/[US] (AllExceptUS)
  • JACOBSON, Stephen, Ernest [US]/[US] (UsOnly)
  • MURPHY, Peter, Michael [US]/[US] (UsOnly)
  • LANGLEY, Melea, Rena [US]/[US] (UsOnly)
Inventors
  • JACOBSON, Stephen, Ernest
  • MURPHY, Peter, Michael
  • LANGLEY, Melea, Rena
Agents
  • MAYER, Nancy, S.
Priority Data
11/115,53327.04.2005US
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) PERFLUOROAMIDATED AND HYDROLYZED MALEIC ANHYDRIDE COPOLYMERS
(FR) COPOLYMERES D'ANHYDRE MALEIQUE PERFLUOROAMIDES ET HYDROLYSES
Abstract
(EN) A composition which provides stain resistance and soil resistance to substrates comprising a copolymer of Formula (1) wherein D is at least one vinyl monomer selected from the group consisting of aryl olefin, vinyl ether, allyl ether, alpha olefin and diene; each M is independently H, NH4, Ca, Mg, Al, or a Group I metal; R is H, a C1 - C16 alkyl group, or an arylalkyl group; Rf is a fully fluorinated straight or branched C2 to C20 aliphatic radical, or mixture thereof, which is optionally interrupted by at least one oxygen atom; x is 1 to about 10, or a mixture thereof; k and h are each independently a positive integer; i and j are each independently zero or a positive integer, provided that i and j are not both simultaneously zero; the molar ratio of k to (h + i + j) is from about 3:1 to about 1:3, and the molar ratio of h to (i + j) is from about 1:99 to about 22:78 is disclosed.
(FR) L'invention concerne une composition qui apporte une résistance aux tâches et une résistance à la salissure à des substrats et qui comprend un copolymère de formule (1) dans laquelle D représente au moins un monomère vinylique sélectionné dans le groupe constitué d'aryloléfine, d'éther vinylique, d'éther allylique, d'alpha oléfine et de diène ; chaque M désigne indépendamment M H, NH4, Ca, Mg, Al, ou un métal du groupe I; R désigne H, un groupe alkyle C1 - C16 ou un groupe arylalkyle; Rf désigne un radical aliphatique fluoré droit ou ramifié C2 à C20 ou un mélange de ceux-ci, qui est éventuellement interrompu par au moins un atome d'oxygène ; x désigne entre 1 et 10 environ, ou un de ses mélanges; k et h désignent chacun indépendamment un entier positif ; i et j représentent chacun indépendamment zéro ou un entier positif, à condition que i et j ne soient pas en même temps égaux à zéro ; le ratio molaire de k par rapport à (h + i + j) est compris entre environ 3:1 et environ 1:3, et le ratio molaire de h par rapport à (i + j) est compris environ entre 1:99 et environ 22:78.
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