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1. (WO2001034555) SYNTHESIS OF STEREOSPECIFIC AND ATACTIC POLY(LACTIC ACID)S
PCT Biblio. Data
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Pub. No.:
WO/2001/034555
International Application No.:
PCT/US2000/028886
Publication Date:
17.05.2001
International Filing Date:
08.11.2000
Chapter 2 Demand Filed:
19.04.2001
IPC:
B01J 23/02
(2006.01),
B01J 23/06
(2006.01),
B01J 31/18
(2006.01),
B01J 31/22
(2006.01),
C08G 63/08
(2006.01),
C08G 63/82
(2006.01)
[IPC code unknown for ERROR IPC Code incorrect: invalid section (A=>H)!][IPC code unknown for ERROR IPC Code incorrect: invalid section (A=>H)!]
B
PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31
Catalysts comprising hydrides, coordination complexes or organic compounds
16
containing coordination complexes
18
containing nitrogen, phosphorus, arsenic or antimony
B
PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31
Catalysts comprising hydrides, coordination complexes or organic compounds
16
containing coordination complexes
22
Organic complexes
[IPC code unknown for ERROR IPC Code incorrect: invalid section (A=>H)!]
C
CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
63
Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
78
Preparation processes
82
characterised by the catalyst used
Applicants:
CORNELL RESEARCH FOUNDATION, INC.
[US/US]; Suite 105, 20 Thornwood Drive, Ithaca, NY 14850 (US)
Inventors:
COATES, Geoffrey, W.
; (US).
CHENG, Ming
; (US).
CHAMBERLAIN, Bradley, M.
; (US)
Agent:
SPECTOR, Eric, S.
; Jones, Tullar & Cooper, P.C., P.O. Box 2266 Eads Station, Arlington, VA 22202 (US)
Priority Data:
60/164,606
10.11.1999
US
Title
(EN)
SYNTHESIS OF STEREOSPECIFIC AND ATACTIC POLY(LACTIC ACID)S
(FR)
SYNTHESE D'ACIDES POLY(LACTIQUES) STEREOSPECIFIQUES ET ATACTIQUES
Abstract:
(EN)
Isotactic poly ((R)-lactic acid) or isotactic poly (S)-lactic arerespectively prepared from (R,R)-lactide and (S,S)-lactide using a catalyst which has a zinc center or a magnesium center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group. Heterotactic poly(lactic acid) is prepared from
rac
-lactide using a catalyst which has a zinc center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group; heterotactic poly(lactic acid) is a novel composition. The catalyst with a magnesium center is a novel catalyst. Syndiotactic poly(lactic acid) is prepared from
meso
-lactide using a syndiotactic poly(lactic acid) effecting catalyst which has a zinc center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group diiminate substituted with isopropyl substituted pheny and the ligand which is not a propagating group and the preferred catalyst contains as the propagating group is isopropoxide. Atactic poly(lactic acid) of polydispersity ranging from 1.15 to 1.40 is prepared in less than 10 minutes by polymerizing
rac
-lactide in the presence of C
1
-C
4
alcohol and a catalyst with a magnesium center and two ligands where one of the ligands is a propagating group and the other of the ligands is not a propagating group.
(FR)
La présente invention concerne la préparation de l'acide poly((R)- lactique) isostatique ou de l'acide poly (S)- lactique isostatique à partir de (R,R)-lactide et (S,S)-lactide avec un catalyseur présentant un centre zinc ou un centre magnésium et deux ligands dont l'un seulement est un groupe de propagation. L'acide poly(lactique) hétérotactique est préparé à partir de
rac
-lactide en utilisant un catalyseur comportant un centre zinc et deux ligands dont l'un seulement est un groupe de propagation; l'acide poly(lactique) hétérotactique étant une nouvelle composition. Le catalyseur comportant un centre magnésium est un nouveau catalyseur. L'acide poly(lactique) syndiotactique est préparé à partir de
meso
-lactide en utilisant un catalyseur effecteur comportant un centre zinc et deux ligands dont l'un seulement est un groupe de propagation; le catalyseur préféré contenant comme ligand qui n'est pas un groupe de propagation du diiminate substitué par un phényle substitué par un isopropyle, le groupe de prolifération étant de l'isopropoxyde. L'acide polylactique de polydispersité compris entre 1,15 et 1,40 est préparé en moins de 10 minutes en polymérisant
rac
-lactide en présence de C
1
-C
4
alcool et d'un catalyseur avec un centre magnésium et deux ligands dont l'un seulement est un groupe de propagation.
Designated States:
CA, JP.
European Patent Office (AT, BE, CH, CY, DE, DK, ES, FI, FR, GB, GR, IE, IT, LU, MC, NL, PT, SE, TR).
Publication Language:
English (
EN
)
Filing Language:
English (
EN
)