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1. WO2000040544 - ALIPHATICALLY UNSATURATED HYDROXY BENZOATES AND PRESERVATIVE COMPOSITIONS THEREOF

Publication Number WO/2000/040544
Publication Date 13.07.2000
International Application No. PCT/US1999/028925
International Filing Date 07.12.1999
Chapter 2 Demand Filed 28.06.2000
IPC
A01N 37/40 2006.01
AHUMAN NECESSITIES
01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
37Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
36containing at least one carboxylic group or a thio-analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio-analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
38having at least one oxygen or sulfur atom attached to an aromatic ring system
40having at least one carboxylic group or a thio-analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
C07C 69/88 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
69Esters of carboxylic acids; Esters of carbonic or haloformic acids
76Esters of carboxylic acids having an esterified carboxyl group bound to a carbon atom of a six-membered aromatic ring
84of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
88with esterified carboxyl groups
CPC
A01N 37/40
AHUMAN NECESSITIES
01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES, AS HERBICIDES
37Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
36containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
38having at least one oxygen or sulfur atom attached to an aromatic ring system
40having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
C07C 69/88
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
69Esters of carboxylic acids; Esters of carbonic or haloformic acids
76Esters of carboxylic acids having a carboxyl group bound to a carbon atom of a six-membered aromatic ring
84of monocyclic hydroxy carboxylic acids, the hydroxy groups and the carboxyl groups of which are bound to carbon atoms of a six-membered aromatic ring
88with esterified carboxyl groups
Applicants
  • ISP INVESTMENTS INC. [US/US]; 300 Delaware Avenue Wilmington, DE 19801, US
Inventors
  • ELDER, Todd; US
  • MERIANOS, John, J.; US
Agents
  • MAUE, Marilyn, J. ; International Specialty Products Building 10 1361 Alps Road Wayne, NJ 07470, US
Priority Data
09/225,62905.01.1999US
Publication Language English (EN)
Filing Language English (EN)
Designated States
Title
(EN) ALIPHATICALLY UNSATURATED HYDROXY BENZOATES AND PRESERVATIVE COMPOSITIONS THEREOF
(FR) HYDROXYBENZOATES ALIPHATIQUEMENT INSATURES ET LEURS COMPOSITIONS DE CONSERVATION
Abstract
(EN)
The hydroxybenzoate compounds of this invention are defined by the formula (I), wherein Y is hydrogen, hydroxy, halo, a C1 to C6 alkyl or a C2 to C6 alkyl ether; R is a C4 to C6 mono- or di- olefinically unsaturated hydrocarbon radical, a C4 to C7 mono- or di- acetylenically unsaturated hydrocarbon radical or a C2 to C3 acetylenically unsaturated hydrocarbon radical when at least one of X and Y is other than hydrogen and X is hydrogen, hydroxy, halo, a C1 to C6 alkyl, a C2 to C6 alkyl ether or (a) in which A is selected from the group of X, B is selected from the group of Y and R1 is hydrogen, hydroxy, C1 to C6 alkyl, C1 to C6 alkoxy or -COOR2 in which R2 is C1 to C6 alkyl, a C2 to C6 olefinically unsaturated hydrocarbon radical or a C2 to C7 acetylenically unsaturated hydrocarbon radical. The invention also pertains to food, beverage, cosmetic, agrichemical and topically applied pharmaceutical compositions containing an effective preservative amount of the hydroxy aliphatically unsaturated benzoate having formula (II), wherein X' is selected from the group of X; Y' is selected from the group of Y and R4 is a C2 to C6 mono- or di-olefinically unsaturated hydrocarbon radical or a C2 to C7 mono- or di- acetylenically unsaturated hydrocarbon radical.
(FR)
Les composés d'hydroxybenzoate, selon l'invention, sont définis par la formule (I), dans laquelle Y est hydrogène, hydroxy, halo, un alkyle C1 à C6 ou un alkyle éther C2 à C6, R est un radical hydrocarbure mono- ou di- insaturé en oléfine C4 à C6, un radical hydrocarbure mono- ou di- insaturé en acétylène C4 à C7, ou un radical hydrocarbure insaturé en acétylène C2 à C3, lorsque au moins un X et un Y sont autres que l'hydrogène, et X est hydrogène, hydroxy, halo, un alkyle C1 à C6 ou un alkyle éther C2 à C6, ou par la formule (a), dans laquelle A est choisi dans le groupe de X; B dans le groupe de Y et R1 est hydrogène, hydroxy, un alkyle C1 à C6, un alkoxy C1 à C6 ou -COOR2, dans lequel R2 est un alkyle C1 à C6, un radical hydrocarbure insaturé en oléfine C2 à C6 ou un radical hydrocarbure insaturé en acétylène C2 à C7. L'invention porte sur des compositions d'aliments, de boissons, des compositions de produits cosmétiques, agrochimiques et pharmaceutiques appliquées localement contenant une dose conservatrice d'hydroxybenzoate aliphatiquement non saturé ayant pour formule (II); dans laquelle X' est choisi dans le groupe de X, Y' est choisi dans le groupe de Y et R4 est un radical hydrocarbure mono- ou di- insaturé en oléfine C2 à C6 ou un radical hydrocarbure mono- ou di- insaturé en acétylène C2 à C7.
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