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1. WO1992016487 - PROCESS FOR PREPARING AN ALKANONE AND/OR ALKANOL

Publication Number WO/1992/016487
Publication Date 01.10.1992
International Application No. PCT/NL1992/000053
International Filing Date 19.03.1992
Chapter 2 Demand Filed 16.10.1992
IPC
B01J 31/02 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
02containing organic compounds or metal hydrides
B01J 31/16 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
16containing coordination complexes
C07C 29/132 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
29Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
132by reduction of an oxygen-containing functional group
C07C 45/33 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
45Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
27by oxidation
32with molecular oxygen
33of CHx-moieties
C07C 45/53 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
45Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
51by pyrolysis, rearrangement or decomposition
53of hydroperoxides
CPC
B01J 21/08
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
08Silica
B01J 2231/70
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2231Catalytic reactions performed with catalysts classified in B01J31/00
70Oxidation reactions, e.g. epoxidation, (di)hydroxylation, dehydrogenation and analogues
B01J 2531/22
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2531Additional information regarding catalytic systems classified in B01J31/00
20Complexes comprising metals of Group II (IIA or IIB) as the central metal
22Magnesium
B01J 2531/46
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2531Additional information regarding catalytic systems classified in B01J31/00
40Complexes comprising metals of Group IV (IVA or IVB) as the central metal
46Titanium
B01J 2531/56
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2531Additional information regarding catalytic systems classified in B01J31/00
50Complexes comprising metals of Group V (VA or VB) as the central metal
56Vanadium
B01J 2531/62
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2531Additional information regarding catalytic systems classified in B01J31/00
60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
62Chromium
Applicants
  • DSM N.V. [NL]/[NL]
Inventors
  • JANSSEN, Ludovicus, Hubertus, Wilhelmus
  • HOOGENDOORN, Peter
  • KRAGTEN, Ubaldus, Franciscus
  • BAUR, Henricus, Anna, Christiaan
Agents
  • DEN HARTOG, Jeroen, Hendrikus, Joseph
Priority Data
910052125.03.1991NL
Publication Language English (EN)
Filing Language English (EN)
Designated States
Title
(EN) PROCESS FOR PREPARING AN ALKANONE AND/OR ALKANOL
(FR) PROCEDE DE PREPARATION D'UN ALCANONE ET/OU D'UN ALCANOL
Abstract
(EN)
The invention relates to a process for preparing an alkanone and/or alkanol by oxidizing an alkane with 3-30 C-atoms, using oxygen, to form an alkyl hydroperoxide, followed by a decomposition of the resulting alkyl hydroperoxide in the presence of a metal compound immobilized on a carrier, which carrier carries aliphatic or aromatic amine groups or sulphide groups. The process is preferably applied to cycloalkanes.
(FR)
Procédé de préparation d'un alcanone et/ou d'un alcanol par l'oxydation à l'aide d'oxygène d'un alcane possédant de 3 à 30 atomes de carbone de manière à former un hydroperoxyde d'alkyle, puis par la décomposition de ce dernier en présence d'un composé métallique immobilisé sur un porteur qui porte des groupes aminés aromatiques ou aliphatiques ou des groupes de sulfure. De préférence, le procédé s'applique aux cycloalcanes.
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