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1. WO1990006810 - LOW PRESSURE RHODIUM CATALYZED HYDROFORMYLATION OF OLEFINS

Publication Number WO/1990/006810
Publication Date 28.06.1990
International Application No. PCT/US1989/005722
International Filing Date 20.12.1989
Chapter 2 Demand Filed 11.07.1990
IPC
B01J 31/24 2006.1
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
16containing coordination complexes
24Phosphines
C07C 45/49 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
45Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
49by reaction with carbon monoxide
C07C 45/50 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
45Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
49by reaction with carbon monoxide
50by oxo-reactions
CPC
B01J 2231/20
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2231Catalytic reactions performed with catalysts classified in B01J31/00
20Olefin oligomerisation or telomerisation
B01J 2531/0208
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2531Additional information regarding catalytic systems classified in B01J31/00
02Compositional aspects of complexes used, e.g. polynuclearity
0202Polynuclearity
0208Bimetallic complexes, i.e. comprising one or more units of two metals, with metal-metal bonds but no all-metal (M)n rings, e.g. Cr2(OAc)4
B01J 2531/54
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2531Additional information regarding catalytic systems classified in B01J31/00
50Complexes comprising metals of Group V (VA or VB) as the central metal
54Bismuth
B01J 2531/822
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2531Additional information regarding catalytic systems classified in B01J31/00
80Complexes comprising metals of Group VIII as the central metal
82Metals of the platinum group
822Rhodium
B01J 31/1895
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
16containing coordination complexes
18containing nitrogen, phosphorus, arsenic or antimony ; as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
1895the ligands containing arsenic or antimony
B01J 31/24
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
16containing coordination complexes
24Phosphines ; , i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
Applicants
  • EASTMAN KODAK COMPANY [US]/[US]
Inventors
  • DEVON, Thomas, James
  • PHILLIPS, Gerald, Wayne
  • PUCKETTE, Thomas, Allen
  • STAVINOHA, Jerome, Leonard
  • VANDERBILT, Jeffrey, James
Agents
  • THOMSEN, J, Fredrick
Priority Data
288,59622.12.1988US
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) LOW PRESSURE RHODIUM CATALYZED HYDROFORMYLATION OF OLEFINS
(FR) HYDROFORMYLATION SOUS BASSE PRESSION D'OLEFINES AVEC UN CATALYSEUR AU RHODIUM
Abstract
(EN) The hydroformylation of olefins with rhodium complex catalysts is described. The catalysts employed comprise a rhodium complex with at least one bidentate ligand having a specified structure (I). Hydroformylation reactions at relatively low temperatures and pressure and yet with high rates of reaction and high selectivity to aldehyde product are obtained by the practice of the present invention.
(FR) L'invention concerne l'hydroformylation d'oléfines avec des catalyseurs de complexe de rhodium. Les catalyseurs utilisés comprennent un complexe de rhodium avec au moins un ligand bidenté ayant une structure spécifique (I). Des réactions d'hydroformylation à des températures et pressions relativement basses mais des vitesses de réaction élevées et une grande sélectivité pour le produit d'aldéhyde sont obtenues par la présente invention.
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