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1. US20180030196 - METHOD FOR MANUFACTURING A POLYURETHANE-MODIFIED FOAM, FOAM OBTAINED, AND USES

Office
United States of America
Application Number 15661329
Application Date 27.07.2017
Publication Number 20180030196
Publication Date 01.02.2018
Publication Kind A1
IPC
C08G 18/08
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
C08J 9/00
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H142
9Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
C08J 9/14
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H142
9Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
04using blowing gases generated by a previously added blowing agent
12by a physical blowing agent
14organic
C08G 18/42
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
42Polycondensates having carboxylic or carbonic ester groups in the main chain
CPC
C08G 18/14
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
14Manufacture of cellular products
C08G 18/4288
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
42Polycondensates having carboxylic or carbonic ester groups in the main chain
4288modified by higher fatty oils or their acids or by resin acids
C08J 9/0061
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G
9Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
0061characterized by the use of several polymeric components
C08J 9/141
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G
9Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
04using blowing gases generated by a previously added blowing agent
12by a physical blowing agent
14organic
141Hydrocarbons
C08G 210/0025
Applicants SOPREMA
UNIVERSITE DE STRASBOURG
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE
Inventors Alice ARBENZ
Stephanie LAURICHESSE
Remi PERRIN
Pierre Etienne BINDSCHEDLER
Luc AVEROUS
Priority Data 1670413 28.07.2016 FR
Title
(EN) METHOD FOR MANUFACTURING A POLYURETHANE-MODIFIED FOAM, FOAM OBTAINED, AND USES
Abstract
(EN)

Disclosed is a method for manufacturing an isocyanurate polyurethane-modified foam, called “PUIR,” including: a) providing an oil or oil mixture at least 50% by weight of the fatty acids having a carbon chain of C18 or more, the fatty acids having an overall iodine number Iiodine of at least 100 g of I2/100 g; b) epoxidating at least 50% of the double bonds in the oil to form the corresponding epoxides; and c) directly reacting, in situ, the epoxides that are obtained above with isocyanate or diisocyanate groups for obtaining corresponding oxazolidone derivatives, without passing through the intermediate formation of polyols obtained from epoxides, in the presence of at least one suitable catalyst and at least one expanding agent, so as to obtain the isocyanurate polyurethane-modified foam “PUIR.” Also disclosed are products, such as rigid insulation material, in particular as a material or panels of rigid insulation for roofing.

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