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1. (US20150141238) Nanoparticle catalyst capable of forming aromatic hydrocarbons from CO2 and H2

Office : United States of America
Application Number: 14603628 Application Date: 23.01.2015
Publication Number: 20150141238 Publication Date: 21.05.2015
Grant Number: 09555405 Grant Date: 31.01.2017
Publication Kind : B2
IPC:
C07C 1/04
C07C 15/00
B01J 23/74
B01J 23/94
B01J 35/02
B01J 23/745
C07C 1/12
B01J 29/14
B01J 35/00
B01J 21/04
B01J 29/10
C07C 1/22
C10L 1/04
B82Y 40/00
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
1
Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
02
from oxides of carbon
04
from carbon monoxide with hydrogen
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
15
Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic part
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70
of the iron group metals or copper
74
Iron group metals
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
90
Regeneration or reactivation
94
of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35
Catalysts, in general, characterised by their form or physical properties
02
Solids
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70
of the iron group metals or copper
74
Iron group metals
745
Iron
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
1
Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
02
from oxides of carbon
12
from carbon dioxide with hydrogen
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
08
of the faujasite type, e.g. type X or Y
10
containing iron group metals, noble metals or copper
14
Iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35
Catalysts, in general, characterised by their form or physical properties
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21
Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
02
Boron or aluminium; Oxides or hydroxides thereof
04
Alumina
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
08
of the faujasite type, e.g. type X or Y
10
containing iron group metals, noble metals or copper
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
1
Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
20
starting from organic compounds containing only oxygen atoms as hetero atoms
22
by reduction
C CHEMISTRY; METALLURGY
10
PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
L
FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K123; LIQUEFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
1
Liquid carbonaceous fuels
04
essentially based on blends of hydrocarbons
B PERFORMING OPERATIONS; TRANSPORTING
82
NANO-TECHNOLOGY
Y
SPECIFIC USES OR APPLICATIONS OF NANO-STRUCTURES; MEASUREMENT OR ANALYSIS OF NANO-STRUCTURES; MANUFACTURE  OR TREATMENT OF NANO-STRUCTURES
40
Manufacture or treatment of nano-structures
Applicants: Kansas State University Research Foundation
Inventors: Hongwang Wang
Stefan H. Bossmann
Donghai Wang
Deryl L. Troyer
Tej Shrestha
Agents: Hovey Williams LLP
Priority Data:
Title: (EN) Nanoparticle catalyst capable of forming aromatic hydrocarbons from CO2 and H2
Abstract: front page image
(EN)

Nanocatalysts and methods of using the same to obtain aromatic hydrocarbon compounds from a source of carbon atoms and a source of hydrogen atoms in a single reaction step is provided. The catalyst comprises an Fe/Fe3O4 nanocatalyst that may be supported on a non-reactive support material such as a zeolite or alumina CO2 and H2 are preferred sources of carbon and hydrogen atoms for the reaction. The aromatic hydrocarbon compounds produced are suitable for direct usage as fuel without need for further refining.