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1. FR2966456 - PROCEDE D'OBTENTION D'ACROLEINE PAR DESHYDRATATION CATALYTIQUE DE GLYCEROL OU DE GLYCERINE

Office France
Application Number 1058767
Application Date 26.10.2010
Publication Number 2966456
Publication Date 27.04.2012
Grant Number 2966456
Grant Date 15.03.2013
Publication Kind B1
IPC
C07C 45/52
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
45Preparation of compounds having C=O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
51by pyrolysis, rearrangement or decomposition
52by dehydration and rearrangement involving two hydroxy groups in the same molecule
C07C 47/22
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
47Compounds having -CHO groups
20Unsaturated compounds having -CHO groups bound to acyclic carbon atoms
21with only carbon-to-carbon double bonds as unsaturation
22Acrylaldehyde; Methacrylaldehyde
CPC
C07C 45/52
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
45Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
51by pyrolysis, rearrangement or decomposition
52by dehydration and rearrangement involving two hydroxy groups in the same molecule
C07C 319/18
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
18by addition of thiols to unsaturated compounds
C07C 319/20
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
20by reactions not involving the formation of sulfide groups
Y02P 20/584
YSECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
20Technologies relating to chemical industry
50Improvements relating to the production of bulk chemicals
584Recycling of catalysts
B01J 23/30
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
16of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
24Chromium, molybdenum or tungsten
30Tungsten
C07C 47/22
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
47Compounds having —CHO groups
20Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
21with only carbon-to-carbon double bonds as unsaturation
22Acryaldehyde; Methacryaldehyde
Applicants ADISSEO FRANCE SAS
LILLE ECOLE CENTRALE
Inventors BELLIERE BACA VIRGINIE
FATAH NOURIA
PAUL SEBASTIEN
PARIENTE STEPHANE
Priority Data 1058767 26.10.2010 FR
Title
(FR) PROCEDE D'OBTENTION D'ACROLEINE PAR DESHYDRATATION CATALYTIQUE DE GLYCEROL OU DE GLYCERINE
Abstract
(FR)
Un procédé continu d'obtention d'acroléine par déshydratation catalytique de glycérol ou de glycérine, en présence d'un catalyseur acide, ledit procédé comprenant la régénération concomitante dudit catalyseur et étant réalisé dans un réacteur à lit fluidisé, ledit réacteur comprenant deux zones, une première zone, ou zone inférieure, dite de régénération du catalyseur dans laquelle un gaz de fluidisation comprenant de l'oxygène est introduit et une seconde zone, ou zone supérieure, dite de réaction dans lequel le glycérol ou la glycérine est introduit et converti en acroléine.