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1. (EP0858470) A SOLVENT-FREE, RADIATION-CURABLE, OPTICAL GLASS FIBER COATING COMPOSITION AND SOLVENT-FREE METHOD FOR MAKING A SOLVENT-FREE, RADIATION-CURABLE, OPTICAL GLASS FIBER COATING COMPOSITION

Office : European Patent Office
Application Number: 96935586 Application Date: 31.10.1996
Publication Number: 0858470 Publication Date: 19.08.1998
Publication Kind : A1
Designated States: BE, CH, DE, DK, FR, GB, IT, LI, NL, SE
Prior PCT appl.: Application Number:NL1996000429 ; Publication Number: Click to see the data
IPC:
C 03C
C 08G
C03C 25/24
C03C 25/10
C08F 2/06
C08F 8/30
C08F 290/12
C08G 18/81
C09D 4/06
G03F 7/027
G03F 7/038
(Deprecated)
C CHEMISTRY; METALLURGY
03
GLASS; MINERAL OR SLAG WOOL
C
CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
25
Surface treatment of fibres or filaments from glass, minerals, or slags
02
Coating
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
70
characterised by the isocyanates or isothiocyanates used
81
Unsaturated isocyanates or isothiocyanates
C CHEMISTRY; METALLURGY
03
GLASS; MINERAL OR SLAG WOOL
C
CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
25
Surface treatment of fibres or filaments from glass, minerals, or slags
10
by coating
24
Coatings containing organic materials
C CHEMISTRY; METALLURGY
03
GLASS; MINERAL OR SLAG WOOL
C
CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
25
Surface treatment of fibres or filaments from glass, minerals, or slags
10
by coating
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2
Processes of polymerisation
04
Polymerisation in solution
06
Organic solvent
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
8
Chemical modification by after-treatment
30
Introducing nitrogen atoms or nitrogen-containing groups
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
290
Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
08
on to polymers modified by introduction of unsaturated side groups
12
Polymers provided for in subclasses C08C or C08F76
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
70
characterised by the isocyanates or isothiocyanates used
81
Unsaturated isocyanates or isothiocyanates
C CHEMISTRY; METALLURGY
09
DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
D
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
4
Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond
06
in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/-C09D187/142
G PHYSICS
03
PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
F
PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
7
Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
004
Photosensitive materials
027
Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
G PHYSICS
03
PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
F
PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
7
Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printed surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
004
Photosensitive materials
038
Macromolecular compounds which are rendered insoluble or differentially wettable
CPC:
G03F 7/0388
C03C 25/106
C03C 25/1065
C08G 18/6229
C08G 18/8158
G03F 7/027
Y10T 428/2938
Applicants: DSM NV
Inventors: TORTORELLO ANTONY J
MURPHY EDWARD J
Priority Data: 9600429 31.10.1996 NL
720995 03.11.1995 US
Title: (DE) EINE LÖSUNGSMITTELFREIE, STRAHLUNGSHÄRTBARE BESCHICHTUNGSZUSAMMENSETZUNGEN FÜR OPTISCHE GLASFASERN UND LÖSUNGSMITTELFREIES VERFAHREN ZUR HERSTELLUNG EINER LÖSUNGSMITTELFREIEN, STRAHLUNGSHÄRTBAREN BESCHICHTUNGSZUSAMMENSETZUNG FÜR OPTISCHE GLASFASERN
(EN) A SOLVENT-FREE, RADIATION-CURABLE, OPTICAL GLASS FIBER COATING COMPOSITION AND SOLVENT-FREE METHOD FOR MAKING A SOLVENT-FREE, RADIATION-CURABLE, OPTICAL GLASS FIBER COATING COMPOSITION
(FR) COMPOSITION SANS SOLVANTS ET DURCISSABLE PAR RAYONNEMENT DESTINEE AU REVETEMENT DE FIBRES OPTIQUES EN VERRE, ET PROCEDE DE PRODUCTION D'UNE TELLE COMPOSITION SANS SOLVANTS
Abstract:
(EN) The invention relates to a solvent-free radiation-curable, optical glass fiber coating composition containing: a) a urethane oligomer having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1.2, having a vinyl addition polymer as backbone; b) a urethane compound having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1, containing an organic moiety having about 5 or more carbon atoms as backbone; c) a reactive diluent. Furthermore, the invention relates to a solvent-free method for producing a solvent-free, radiation curable urethane oligomer composition.
(FR) Cette invention concerne une composition sans solvants et durcissable par rayonnement qui est destinée au revêtement de fibres optiques en verre, et qui comprend les éléments suivants: (a) un oligomère d'uréthane possédant un groupe fonctionnel capable d'une polymérisation en présence d'un rayonnement actinique, ayant une fonctionnalité moyenne d'au moins environ 1,2, et possédant un polymère d'addition vinyllique à titre de squelette; (b) un composé d'uréthane possédant un groupe fonctionnel capable d'une polymérisation en présence d'un rayonnement actinique, ayant une fonctionnalité moyenne d'au moins environ 1, et contenant à titre de squelette, un fragment organique comportant environ 5 atomes de carbone ou plus; et (C) un réactif diluant. Cette invention concerne également un procédé ne faisant pas appel à des solvants et permettant de produire une composition à base d'oligomères d'uréthane durcissable par rayonnement et sans solvants.
Also published as:
JPH11514622 CN1205718CA2236667KR1019990067326AU1996073432WO/1997/016469