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1. (EP0514557) COATING SOLUTION FOR FORMING TRANSPARENT ELECTRICALLY CONDUCTIVE FILM, METHOD OF PREPARATION THEREOF, ELECTRICALLY CONDUCTIVE SUBSTRATE, METHOD OF PREPARATION THEREOF, AND DISPLAY DEVICE HAVING TRANSPARENT ELECTRICALLY CONDUCTIVE SUBSTRATE
Office : European Patent Office
Application Number: 92902474 Application Date: 21.11.1991
Publication Number: 0514557 Publication Date: 25.11.1992
Publication Kind : B1
Designated States: DE, FR, GB, IT, NL
Prior PCT appl.: Application Number:JP1991001603 ; Publication Number: Click to see the data
IPC:
B05D 3/02
B05D 3/04
B05D 3/06
C03C 17/00
C09D 5/24
G02F 1/1343
H01B 1/20
H01B 1/22
H01B 1/24
H05K 1/09
B PERFORMING OPERATIONS; TRANSPORTING
05
SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
D
PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
3
Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
02
by baking
B PERFORMING OPERATIONS; TRANSPORTING
05
SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
D
PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
3
Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
04
by exposure to gases
B PERFORMING OPERATIONS; TRANSPORTING
05
SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
D
PROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
3
Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
06
by exposure to radiation
C CHEMISTRY; METALLURGY
03
GLASS; MINERAL OR SLAG WOOL
C
CHEMICAL COMPOSITION OF GLASSES, GLAZES, OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
17
Surface treatment of glass, e.g. of devitrified glass, not in the form of fibres or filaments, by coating
C CHEMISTRY; METALLURGY
09
DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
D
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
5
Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
24
Electrically-conducting paints
G PHYSICS
02
OPTICS
F
DEVICES OR ARRANGEMENTS, THE OPTICAL OPERATION OF WHICH IS MODIFIED BY CHANGING THE OPTICAL PROPERTIES OF THE MEDIUM OF THE DEVICES OR ARRANGEMENTS FOR THE CONTROL OF THE INTENSITY, COLOUR, PHASE, POLARISATION OR DIRECTION OF LIGHT, e.g. SWITCHING, GATING, MODULATING OR DEMODULATING; TECHNIQUES OR PROCEDURES FOR THE OPERATION THEREOF; FREQUENCY-CHANGING; NON-LINEAR OPTICS; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
1
Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
01
for the control of the intensity, phase, polarisation or colour
13
based on liquid crystals, e.g. single liquid crystal display cells
133
Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
1333
Constructional arrangements
1343
Electrodes
H ELECTRICITY
01
BASIC ELECTRIC ELEMENTS
B
CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
1
Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
20
Conductive material dispersed in non-conductive organic material
H ELECTRICITY
01
BASIC ELECTRIC ELEMENTS
B
CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
1
Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
20
Conductive material dispersed in non-conductive organic material
22
the conductive material comprising metals or alloys
H ELECTRICITY
01
BASIC ELECTRIC ELEMENTS
B
CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
1
Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
20
Conductive material dispersed in non-conductive organic material
24
the conductive material comprising carbon-silicon compounds, carbon, or silicon
H ELECTRICITY
05
ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
K
PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
1
Printed circuits
02
Details
09
Use of materials for the metallic pattern
CPC:
H01B 1/24
B05D 3/0254
B05D 3/046
B05D 3/067
C03C 17/007
C03C 17/009
C03C 2217/45
C03C 2217/475
C03C 2217/476
C09D 5/24
G02F 1/13439
H01B 1/20
H01B 1/22
H05K 1/095
Y10T 428/31612
Y10T 428/31663
Applicants: CATALYSTS & CHEM IND CO
Inventors: HIRAI T
KOMATSU M
NAKASHIMA A
ABE Y
IWASAKI Y
Priority Data: 31657590 21.11.1990 JP
9065091 22.04.1991 JP
9101603 21.11.1991 JP
Title: (DE) ÜBERZUGSLÖSUNG ZUR BILDUNG EINES DURCHSICHTIGEN, LEITFÄHIGEN FILMS, VERFAHREN ZU DEREN HERSTELLUNG, LEITFÄHIGES SUBSTRAT, VERFAHREN ZUR DESSEN HERSTELLUNG, UND ANZEIGEVORRICHTUNG MIT EINEM DURCHSICHTIGEN, LEITFÄHIGEN SUBSTRAT
(EN) COATING SOLUTION FOR FORMING TRANSPARENT ELECTRICALLY CONDUCTIVE FILM, METHOD OF PREPARATION THEREOF, ELECTRICALLY CONDUCTIVE SUBSTRATE, METHOD OF PREPARATION THEREOF, AND DISPLAY DEVICE HAVING TRANSPARENT ELECTRICALLY CONDUCTIVE SUBSTRATE
(FR) SOLUTION DE REVETEMENT FORMANT UN FILM ELECTROCONDUCTEUR TRANSPARENT, PROCEDE DE PREPARATION DE CETTE SOLUTION, SUBSTRAT ELECTROCONDUCTEUR, PROCEDE DE PREPARATION DE CE SUBSTRAT, ET DISPOSITIF D'AFFICHAGE COMPORTANT UN SUBSTRAT ELECTROCONDUCTEUR
Abstract: front page image
(EN) An electrically conductive substrate has on the surface thereof a transparent conductive film made from a coating solution that is obtained by dispersing or dissolving in the water and/or an organic solvent a matrix composed of electrically conductive particles having: (a) an average particles diameter of smaller than 500 ANGSTROM ; (b) the particles of smaller than 600 ANGSTROM being contained in an amount of greater than 60 % by weight; (c) the particles of smaller than 100 ANGSTROM being contained in an amount of greater than 5 % by weight; (d) the particles of greater than 1000 ANGSTROM being contained in an amount of smaller than 15 % by weight; and a silica polymer having: (A) an average polymerization degree of 1,500 to 10,000; (B) the polymer with a polymerization degree of smaller than 3,000 being contained in an amount of smaller than 50 % by weight; (C) the polymer with a polymerization degree of greater than 10,000 being contained in an amount of smaller than 20 % by weight. The electrically conductive substrate has excellent adhering property, surface smoothness, durability and transparency. The display device having a transparent electrically conductive substrate on a display panel portion exhibits excellent resolution and offers vivid image at all times.
(FR) Substrat électroconducteur comportant en surface un fil conducteur transparent composé d'une solution de revêtement que l'on obtient en dispersant ou en dissolvant dans l'eau et/ou dans un solvant organique une matrice composée de particules électroconductrices présentant les caractéristiques suivantes: (a) le diamètre moyen des particules est inférieur à 500 Å; (b) les particules de diamètre inférieur à 600 Å sont présentes dans une quantité supérieure à 60 % en poids; (c) les particules d'un diamètre inférieur à 100 Å sont présentes dans une quantité supérieure à 5 % en poids; (d) les particules d'un diamètre supérieur à 1000 Å sont présentes dans une quantité inférieure à 15 % en poids. On disperse ou dissout également un polymère de silice présentant les caractéristiques suivantes: (A) le degré de polymérisation moyen du polymère est compris entre 1500 et 10000; (B) le polymère présentant un degré de polymérisation inférieur à 3000 est présent dans une quantité inférieure à 50 % en poids; (C) le polymère présentant un degré de polymérisation supérieur à 10000 est présent dans une quantité inférieure à 20 %. Le substrat électroconducteur présente d'excellentes caractéristiques d'adhérence, d'égalité de surface, de durabilité et de transparence. Un dispositif d'affichage comportant un panneau d'affichage doté du substrat électroconducteur transparent ci-décrit présente une excellente définition et offre en toutes circonstances une image bien contrastée.
Also published as:
US5376308JP3280667KR1019920703742WO/1992/009665