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1. CN103180365 - Conductive aniline polymer, method for producing same, and method for producing conductive film

Office China
Application Number 201180051856.6
Application Date 25.10.2011
Publication Number 103180365
Publication Date 26.06.2013
Grant Number 103180365
Grant Date 18.02.2015
Publication Kind B
IPC
C08G 73/00
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
73Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen or carbon, not provided for in groups C08G12/-C08G71/238
C08J 5/18
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H142
5Manufacture of articles or shaped materials containing macromolecular substances
18Manufacture of films or sheets
CPC
H01B 1/128
HELECTRICITY
01BASIC ELECTRIC ELEMENTS
BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
1Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
06mainly consisting of other non-metallic substances
12organic substances
124Intrinsically conductive polymers
128comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes
B05D 5/12
BPERFORMING OPERATIONS; TRANSPORTING
05SPRAYING OR ATOMISING IN GENERAL; APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
DPROCESSES FOR APPLYING LIQUIDS OR OTHER FLUENT MATERIALS TO SURFACES, IN GENERAL
5Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
12to obtain a coating with specific electrical properties
C08G 73/0266
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
73Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
02Polyamines
026Wholly aromatic polyamines
0266Polyanilines or derivatives thereof
C08L 79/02
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
79Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
02Polyamines
C09D 5/24
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
5Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced
24Electrically-conducting paints
C09D 179/02
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
179Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
02Polyamines
Applicants Mitsubishi Rayon Co., Ltd.
Inventors Yamada Kohei
Horiuchi Yasushi
Hachiya Yukiko
Uzawa Masashi
Sakai Takahiro
Takagi Tamae
Agents zhong jing jin xianyang
Priority Data 2010-240039 26.10.2010 JP
2011-006849 17.01.2011 JP
2011-032053 17.02.2011 JP
2011-071517 29.03.2011 JP
2011-083579 05.04.2011 JP
Title
(EN) Conductive aniline polymer, method for producing same, and method for producing conductive film
(ZH) 导电性苯胺系聚合物及其制造方法、导电性膜的制造方法
Abstract
(EN)
This conductive aniline polymer has a unit represented by formula (1). When the molecular weight distribution of this conductive aniline polymer is determined by gel permeation chromatography and the retention time is converted into a molecular weight (M) in terms of sodium polystyrene sulfonate, the area ratio of the area (X) of a region where the molecular weight (M) is 15,000 Da or more relative to the area (Y) of a region where the molecular weight (M) is less than 15,000 Da, namely X/Y is 1.20 or more. A method for producing this conductive aniline polymer comprises: a polymerization step (Z1) wherein a specific aniline derivative (A) is polymerized in a solution, which contains a basic compound (B), a solvent (C) and an oxidizing agent (D), at a liquid temperature of less than 25 DEG C; or a polymerization step (Z2) wherein a specific aniline derivative (A) and an oxidizing agent (D) are added into a liquid, wherein a conductive aniline polymer (P-1) having a unit represented by formula (1) is dissolved or dispersed in a solvent (C), and polymerized therein.

(ZH)

本发明的导电性苯胺系聚合物具有下述式(1)表示的单元,通过凝胶渗透色谱测定分子量分布将保持时间换算为聚苯乙烯磺酸钠换算的分子量(M),该分子量(M)中,15000Da以上的区域的面积(X)与不到15000Da的区域的面积(Y)的面积比(X/Y)为1.20以上。另外,本发明的导电性苯胺系聚合物的制造方法具有将特定的苯胺衍生物(A)在含有碱性化合物(B)、溶剂(C)和氧化剂(D)的溶液中,在液温不到25℃下聚合的聚合工序(Z1),或者在具有下述式(1)表示的单元的导电性苯胺系聚合物(P-1)在溶剂(C)中溶解或分散的液体中,添加特定的苯胺衍生物(A)和氧化剂(D)而聚合的聚合工序(Z2)。