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1. CN110099885 - ETHYLENE OLIGOMERIZATION PROCESSES

Office
China
Application Number 201780080623.6
Application Date 22.12.2017
Publication Number 110099885
Publication Date 06.08.2019
Publication Kind A
IPC
C07C 2/32
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
02by addition between unsaturated hydrocarbons
04by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
06of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
08Catalytic processes
26with hydrides or organic compounds
32as complexes, e.g. acetyl-acetonates
C07C 11/02
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
11Acyclic unsaturated hydrocarbons
02Alkenes
C07C 11/107
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
11Acyclic unsaturated hydrocarbons
02Alkenes
107with six carbon atoms
CPC
C07C 2/32
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
02by addition between unsaturated hydrocarbons
04by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
06of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
08Catalytic processes
26with hydrides or organic compounds
32as complexes, e.g. acetyl-acetonates
C07C 2531/14
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2531Catalysts comprising hydrides, coordination complexes or organic compounds
02containing organic compounds or metal hydrides
12containing organo-metallic compounds or metal hydrides
14of aluminium or boron
C07C 2531/22
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2531Catalysts comprising hydrides, coordination complexes or organic compounds
16containing coordination complexes
22Organic complexes
Y02P 20/52
YSECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
20Technologies relating to chemical industry
50Improvements relating to the production of bulk chemicals
52using catalysts, e.g. selective catalysts
B01J 31/143
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
02containing organic compounds or metal hydrides
12containing organo-metallic compounds or metal hydrides
14of aluminium or boron
143of aluminium
B01J 31/22
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
16containing coordination complexes
22Organic complexes
Applicants CHEVRON PHILLIPS CHEMICAL CO., LTD.
切弗朗菲利浦化学公司
Inventors BISCHOF STEVEN M
S·M·比索夫
SMALL BROOKE L
B·L·斯马尔
Agents 北京纪凯知识产权代理有限公司 11245
Priority Data 15394411 29.12.2016 US
Title
(EN) ETHYLENE OLIGOMERIZATION PROCESSES
(ZH) 乙烯低聚方法
Abstract
(EN)
A process comprising A) continuously introducing into a reaction zone i) ethylene, ii) an iron salt, iii) a pyridine bisimine, iv) an organoaluminum compound, and v) an organic reaction medium, and B)forming an oligomer product in the reaction zone, the reaction zone having i) an iron of the iron salt concentration in a range of 5 x 10-4 mmol/kg to 5 x 10-3 mmol/kg, ii) an aluminum of the organoaluminum compound to iron of the iron salt molar ratio in a range of 300:1 to 800:1, ii) an ethylene partial pressure in a range of 750 psig to 1200 psig, iv) an ethylene to organic reaction medium mass ratio in a range of 0.8 to 4.5, v) a temperature in a range of 75 DEG C to 95 DEG C, and optionally vi) a hydrogen partial pressure of at least 5 psi.

(ZH)
方法包含A)向反应区中连续引入i)乙烯、ii)铁盐、iii)吡啶双亚胺、iv)有机铝化合物,和v)有机反应介质,和B)在所述反应区中形成低聚物产物,所述反应区具有i)在5×10‑4mmol/kg至5×10‑3mmol/kg范围内的所述铁盐的铁浓度、ii)在300:1至800:1范围内的所述有机铝化合物的铝与所述铁盐的铁的摩尔比、ii)在750psig至1200psig范围内的乙烯分压、iv)在0.8至4.5范围内的乙烯与有机反应介质的质量比、v)在75℃至95℃范围内的温度,和任选地vi)至少5psi的氢分压。