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1. (JP2004000894) PRODUCTION METHOD OF RUTHENIUM-CARRIED ALUMINA AND ALCOHOL OXIDATION METHOD

Office : Japan
Application Number: 2002345108 Application Date: 28.11.2002
Publication Number: 2004000894 Publication Date: 08.01.2004
Grant Number: 4250954 Grant Date: 08.04.2009
Publication Kind : B2
IPC:
B01J 23/46
B01J 37/3
C07B 61/0
C07C 45/38
C07C 45/39
C07C 47/2
C07C 47/127
C07C 47/21
C07C 47/232
C07C 47/54
C07C 47/55
C07C 47/575
C07C 49/4
C07C 49/203
C07C 49/395
C07C 49/403
C07C 49/413
C07C 49/78
C07C 51/235
C07C 53/126
C07C 201/12
C07C 205/44
C07D 333/22
B01J 21/4
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
38
of noble metals
40
of the platinum group metals
46
Ruthenium, rhodium, osmium or iridium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
02
Impregnation, coating or precipitation
03
Precipitation; Co-precipitation
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
B
GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
61
Other general methods
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
45
Preparation of compounds having CO groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
27
by oxidation
32
with molecular oxygen
37
of C-O- functional groups to CO groups
38
being a primary hydroxy group
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
45
Preparation of compounds having CO groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
27
by oxidation
32
with molecular oxygen
37
of C-O- functional groups to CO groups
39
being a secondary hydroxy group
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
47
Compounds having -CHO groups
02
Saturated compounds having -CHO groups bound to acyclic carbon atoms or to hydrogen
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
47
Compounds having -CHO groups
02
Saturated compounds having -CHO groups bound to acyclic carbon atoms or to hydrogen
12
containing more than one -CHO group
127
Glyoxal
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
47
Compounds having -CHO groups
20
Unsaturated compounds having -CHO groups bound to acyclic carbon atoms
21
with only carbon-to-carbon double bonds as unsaturation
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
47
Compounds having -CHO groups
20
Unsaturated compounds having -CHO groups bound to acyclic carbon atoms
228
containing six-membered aromatic rings, e.g. phenylacetaldehyde
232
having unsaturation outside the aromatic rings
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
47
Compounds having -CHO groups
52
Compounds having -CHO groups bound to carbon atoms of six-membered aromatic rings
54
Benzaldehyde
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
47
Compounds having -CHO groups
52
Compounds having -CHO groups bound to carbon atoms of six-membered aromatic rings
55
containing halogen
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
47
Compounds having -CHO groups
52
Compounds having -CHO groups bound to carbon atoms of six-membered aromatic rings
575
containing ether groups, groups, groups, or groups
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
49
Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
04
Saturated compounds containing keto groups bound to acyclic carbon atoms
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
49
Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
20
Unsaturated compounds containing keto groups bound to acyclic carbon atoms
203
with only carbon-to-carbon double bonds as unsaturation
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
49
Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
385
Saturated compounds containing a keto group being part of a ring
395
of a five-membered ring
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
49
Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
385
Saturated compounds containing a keto group being part of a ring
403
of a six-membered ring
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
49
Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
385
Saturated compounds containing a keto group being part of a ring
413
of a seven- to twelve-membered ring
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
49
Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
76
Ketones containing a keto group bound to a six-membered aromatic ring
78
Acetophenone
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
51
Preparation of carboxylic acids or their salts, halides, or anhydrides
16
by oxidation
21
with molecular oxygen
23
of oxygen-containing groups to carboxyl groups
235
of -CHO groups or primary alcohol groups
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
53
Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
126
Acids containing more than four carbon atoms
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
201
Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
06
Preparation of nitro compounds
12
by reactions not involving the formation of nitro groups
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
205
Compounds containing nitro groups bound to a carbon skeleton
44
the carbon skeleton being further substituted by -CHO groups
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
333
Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
02
not condensed with other rings
04
not substituted on the ring sulfur atom
06
with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
22
Radicals substituted by doubly bound hetero atoms, or by two hetero atoms other than halogen singly bound to the same carbon atom
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21
Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
02
Boron or aluminium; Oxides or hydroxides thereof
04
Alumina
Applicants: SUMITOMO CHEM CO LTD
住友化学株式会社; 東京都中央区新川二丁目27番1号
Inventors: MIZUNO TETSUTAKA
水野 哲孝
YAMAGUCHI KAZUYA
山口 和也
ISHIDA HAJIME
石田 一
Priority Data: 2002126189 26.04.2002 JP
2002345108 28.11.2002 JP
Title: (EN) PRODUCTION METHOD OF RUTHENIUM-CARRIED ALUMINA AND ALCOHOL OXIDATION METHOD
(JA) ルテニウム担持アルミナの製造方法およびアルコールの酸化方法
Abstract:
(EN) PROBLEM TO BE SOLVED: To efficiently produce a ketone, an aldehyde, a carboxylic acid, and the like by oxidizing an alcohol at a high conversion ratio by using a ruthenium-based catalyst having excellent alcohol oxidation activity.

SOLUTION: The ruthenium-carried alumina is produced by suspending alumina in a solution containing trivalent ruthenium and then adding a base. Using the ruthenium-carried alumina obtained in such a manner, a carbonyl compound is produced by bringing an alcohol into contact with oxygen in molecular state in the presence of the catalyst.

COPYRIGHT: (C)2004,JPO
(JA)


【課題】優れたアルコール酸化活性を有するルテニウム触媒を用いて、アルコールを高い転化率で酸化して、ケトン、アルデヒド、カルボン酸等を生産性良く製造すること。
【解決手段】三価のルテニウムを含む溶液にアルミナを懸濁させた後、塩基を加えることにより、ルテニウム担持アルミナを製造する。
こうして得られたルテニウム担持アルミナを触媒として用い、この触媒の存在下にアルコールを分子状酸素と接触させることにより、カルボニル化合物を製造する。
【選択図】 なし