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1. WO2020139566 - PESTICIDAL COMPOSITIONS AND METHODS

Note: Text based on automatic Optical Character Recognition processes. Please use the PDF version for legal matters

[ EN ]

WE CLAIM

1. A molecule having the structure of Formula A:


Formula A wherein:

(A) Ar1 is selected from

(1) furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, thienyl, or

(2) substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, or substituted thienyl,

wherein said substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, and substituted thienyl have one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), SS(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, or S(=O)nNRxRy, or (Het-1),

wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, phenoxy, and (Het-1) substituent may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-Cx alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)(C1-C8

alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)OC1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl )3, S(=O)nNRxRy, or (Het-1);

(B) Het is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur, or oxygen, and where Ar1 and Ar2 are not ortho to each other (but may be meta or para, such as, for a five-membered ring they are 1,3 and for a 6-membered ring they are either 1,3 or 1,4) and where said heterocyclic ring may also be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)NRxRy, (C1-C8 alkyl)NRxRy , C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl) S (=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, or S(=O)nNRxRy,

wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, and phenoxy substituent may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, OXO, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl),

(C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, or S(=O)nNRxRy;

(C) Ar2 is selected from

(1) furanyl, phenyl, pyridazinyl, pyridyl, pyrimidinyl, thienyl, or

(2) substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, or substituted thienyl,

wherein said substituted furanyl, substituted phenyl, substituted pyridazinyl, substituted pyridyl, substituted pyrimidinyl, and substituted thienyl, have one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(=O)nNRxRy, or (Het-1),

wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, phenoxy, and (Het-1) substituent may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-Cx alkyl, C1-Cx haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(=O)nNRxRy, or (Het-1);

(D) L is linker selected from

(1) a bond,

(2) -CR4R5-CR6R7-,or

(3) -CR4=CR6-,

wherein each of R4, R5, R6, and R7 is selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, C2-C8 haloalkynyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C3-C8 cycloalkenyl, C3-C8 halocycloalkenyl, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(=O)n(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C3-C8 cycloalkyl), S(=O)n(C1-C8 haloalkyl), S(=O)n(C3-C8 halocycloalkyl), phenyl, or phenoxy;

(E) R4 and R6 together can optionally form a 3 - to 7-membered saturated or unsaturated ring which may contain C=O, C=S, N, S or O, and is optionally substituted with H, OH, F, Cl, Br, I, CN, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 hydroxyalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C3-C6 hydroxycycloalkyl, C3-C6 cycloalkoxy, C3-C6 halocycloalkoxy, C3-C6 hydroxycycloalkoxy, C1-C6 alkoxy, C1-C6 haloalkoxy, C2-C6 alkenyl, C3-C6 cycloalkenyl, C2-C6 alkynyl, C3-C6 cycloalkynyl, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), OSO2(C1-C6 alkyl), OSO2(C1-C6 haloalkyl), C(=O)H, C(=O)OH, C(=O)NRxRy, (C1-C6 alkyl)NRxRy, C(=O)(C1-C6 alkyl), C(=O)O(C1-C6 alkyl), C(=O)(C1-C6 haloalkyl), C(=O)O(C1-C6 haloalkyl), C(=O)(C3-C6 cycloalkyl), C(=O)O(C3-C6 cycloalkyl), C(=O)(C2-C6 alkenyl), C(=O)O(C2-C6 alkenyl), (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C6 alkyl)S(=O)n(C1-C6 alkyl), C(=O)(C1-C6 alkyl)C(=O)O(C1-C6 alkyl), phenyl, phenoxy, and Het-1;

(F) Q1 is selected from O or S;

(G) Q2 is selected from O or S;

(H) R1 is selected from (J), H, C1-C8 alkyl, C3-C8 cycloalkyl, C2-C8 alkenyl, C2-C8 alkynyl, C(=O)(C1-C8 alkyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, C(=O)(Het-1), (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-O- C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-O-C(=O)NRxRy, (C1-C8 alkyl)-C(=O)N(Rx)(C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(=O)(Het-1), (C1-C8 alkyl)-C(=O)N(Rx)(C1-C8

alkyl )N(Ry)C(=O)0H, (C1-C8 alkyl)-C(=O)N(Rx)(C1-C8 alkyl)N(Rx)(Ry), (C1-C8 alkyl)-C(=O)N(RX)(CI-C8 alkyl )N(Ry)C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-C(=O)N(Rx)(C1-C8 alkyl)(N(Ry)C(=O)O-(C1-C8 alkyl)C(=O)0H, (C1-C8 alkyl)-C(=O)(Het-1)C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C3-C8 cycloalkyl), (C1-C8 alkyl)-OC(=O)-(Het-1), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl)N(Rx)C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-NRxRy, (C1-C8 alkyl)-S-(Het-1), (C1-C8 alkyl) S(=O)n(Het-1), or (C1-C8 alkyl)-O-(Het-1),

wherein each alkyl, cycloalkyl, phenyl, and (Het-1) are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)H, C(=O)OH, C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(=O)nNRxRy, or (Het-1);

(I) R2 is selected from (J), H, OH, SH, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)H, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, C(=O)(Het-1), (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-O-C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-O-C(=O)NRxRy, (C1-C8 alkyl)-C(=O)N(RX)(C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(=O)(Het-1), (C1-C8 alkyl)-C(=O)N(RX)(CI-C8 alkyl)N(Ry)C(=O)0H, (C1-C8 alkyl)-C(=O)N(Rx)(C1-C8 alkyl)N(Rx)(Ry), (C1-C8 alkyl)-C(=O)N(Rx)(C1-C8 alkyl)N(Ry)C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-C(=O)N(RX)(CI-C8 alkyl)(N(Ry)C(=O)O-(C1-C8 alkyl)C(=O)0H, (C1-C8 alkyl)-C(=O)(Het-1)C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C3-C8 cycloalkyl), (C1-C8 alkyl)-OC(=O)-(Het-1), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl)N(Rx)C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-NRxRy, (C1-C8 alkyl)-S-(Het-1), (C1-C8 alkyl)S(=O)n(Het-1), or (C1-C8 alkyl)-O-(Het-1),

wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkoxy, halocycloalkoxy, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, and (Het-1), are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)H, C(=O)OH, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, halophenyl, phenoxy, and (Het-1);

(J) R1 and R2 may be a 1- to 4-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and together with (Q2)(C)(N) forms a 4- to 7-membered cyclic structure, wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl),

S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)H, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, substituted phenyl, phenoxy, or (Het-1);

(K) R3 is selected from C3-C8 cycloalkyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, (C2-C8 alkenyl)-O-phenyl, (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-O-(Het-1), wherein the C3-C8 cycloalkyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, (C2-C8 alkenyl)-O-phenyl, (Het-1), (C1-C8 alkyl)-(Het-1), or (C1-C8 alkyl)-O-(Het-1) may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, OXO, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)O(C1-C8 haloalkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, phenoxy, Si(C1-C8 alkyl)3, S(=O)nNRxRy, or (Het-1) or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected fromH, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), phenyl, and oxo;

(L) Rx and Ry are independently selected from H, OH, SH, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8

alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)H, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, C(=O)(Het-1), (Het-1), (C1-C8 alkyl)-(Het-1), (C1-C8 alkyl)-C(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-O-C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-C(=O)(Het-1), (C1-C8 alkyl)-C(=O)(Het- 1 )C(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)O-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C1-C8 alkyl), (C1-C8 alkyl)-OC(=O)-(C3-C8 cycloalkyl), (C1-C8 alkyl)-OC(O)-(Het-1), (C1-C8 alkyl)-S-(Het-1), (C1-C8 alkyl)S(=O)n(Het-1), or (C1-C8 alkyl)-O-(Het-1), wherein each alkyl, haloalkyl, cycloalkyl, halocycloalkyl, cycloalkoxy, halocycloalkoxy, alkoxy, haloalkoxy, alkenyl, cycloalkenyl, haloalkenyl, alkynyl, phenyl, and (Het-1), are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-Cx alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-Cx haloalkenyl, C2-Cx alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)H, C(=O)OH, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, halophenyl, phenoxy, and (Het-1),

or Rxand Ry together can optionally form a 5- to 7-membered saturated or unsaturated cyclic group which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and where said cyclic group may be substituted with H, F, Cl, Br, I, CN, OH, SH, NO2, OXO, thioxo, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-Cx haloalkenyl, C2-Cx alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, substituted phenyl, phenoxy, and (Het-1);

(M) (Het-1) is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, wherein said heterocyclic ring may also be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, oxo, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)O(C1-C8 haloalkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, and phenoxy,

wherein each alkyl, cycloalkyl, alkoxy, alkenyl, alkynyl, phenyl, and phenoxy may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, OXO, thioxo, NRxRy, C1-C8 alkyl, C1-C8 haloalkyl, C3-C8 cycloalkyl, C3-C8 halocycloalkyl, C3-C8 cycloalkoxy, C3-C8 halocycloalkoxy, C1-C8 alkoxy, C1-C8 haloalkoxy, C2-C8 alkenyl, C3-C8 cycloalkenyl, C2-C8 haloalkenyl, C2-C8 alkynyl, S(=O)n(C3-C8 cycloalkyl), S(=O)n(C3-C8 halocycloalkyl), S(=O)n(C1-C8 alkyl), S(=O)n(C1-C8 haloalkyl), OSO2(C1-C8 alkyl), OSO2(C1-C8 haloalkyl), C(=O)H, C(=O)NRxRy, (C1-C8 alkyl)NRxRy, C(=O)(C1-C8 alkyl), C(=O)O(C1-C8 alkyl), C(=O)(C1-C8 haloalkyl), C(=O)O(C1-C8 haloalkyl), C(=O)(C3-C8 cycloalkyl), C(=O)O(C3-C8 cycloalkyl), C(=O)(C2-C8 alkenyl), C(=O)O(C2-C8 alkenyl), (C1-C8 alkyl)O(C1-C8 alkyl), (C1-C8 alkyl)S(=O)n(C1-C8 alkyl), (C1- C8 alkyl)OC(=O)(C1-C8 alkyl), (C1-C8 alkyl)OC(=O)O(C1-C8 alkyl), C(=O)(C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)O(C1-C8 alkyl), (C1-C8 alkyl)C(=O)(C1-C8 alkyl), (C1-C8 alkyl)phenyl, (C1-C8 alkyl)-O-phenyl, phenyl, and phenoxy; and

(N) n is each individually 0, 1, or 2.

2. The molecule of claim 1, having the structure of Formula One, Formula Two, or Formula Three:


Formula One


Formula Two, or


Formula Three wherein:

(A) Ar1 is a phenyl or substituted phenyl having one or more substituents independently selected from C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy and C1-C6 haloalkoxy;

(B) Het is triazolyl;

(C) Ar2 is a phenyl or a substituted phenyl having one or more substituents independently selected from F, Cl, Br, I, CN, NO2, NRxRy, C1-C6 alkyl, C1-C6 alkoxy, and C1-C6 haloalkyl;

(D) Each R4, R5, R6, and R7 is selected from a H, F, Cl, Br, I, CN, oxo, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, C2-C6 alkynyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 cycloalkenyl, C3-C6 halocycloalkyl, and phenyl;

(E) R1 is selected from (J), H, C1-C6 alkyl or C2-C6 alkenyl, wherein said alkyl or alkenyl is optionally substituted with a C3-C6 cycloalkyl or C1-C6 alkoxy;

(F) R2 is selected from (J), H, OH, SH, C1-C6 alkyl or C2-C6 alkenyl, wherein said alkyl or alkenyl is optionally substituted with a C3-C6 cycloalkyl or C1-C6 alkoxy;

(G) R3 is phenyl or (Het-1), wherein the phenyl or (Het-1) may be optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, (C1-C6 alkyl)O(C1-C6 alkyl), (C1-C8 alkyl)O(C1-C8 haloalkyl), (C1-C6 alkyl)S(=O)n(C1-C6 alkyl), C1-C6 alkoxy, C1-C6 haloalkoxy, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), phenyl, and oxo or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected fromH, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(=O)n(C1-C6 alkyl), and S(=O)n(C1-C6 haloalkyl);

(H) Rx and Ry are independently selected from H, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C3-C6 halocycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, and phenyl;

(I) (Het-1) is a 5- or 6-membered, saturated or unsaturated, heterocyclic ring, containing one or more heteroatoms independently selected from nitrogen, sulfur or oxygen, wherein said heterocyclic ring may also be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), phenyl, and oxo; and

(J) R1 and R2 may be a 1- to 4-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and together with (Q2)(C)(N) forms a 4- to 7-membered cyclic structure, wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(=O)n(C1-C6 alkyl), S(=O)n(C1-C6 haloalkyl), phenyl, and oxo.

3. The molecule of claim 1, wherein Ar1 is a substituted phenyl having one or more substituents independently selected from OCF3, OCF2CF3, and CF3.

4. The molecule of claim 1, wherein Het is 1,2,4-triazolyl.

5. The molecule of claim 1, wherein Ar2 is a phenyl.

6. The molecule of claim 1, wherein Ar2 is a substituted phenyl having one or more substituents independently selected from H, F, Cl, Br, I, CN, C1-C6 alkyl, and C1-C6 alkoxy.

7. The molecule of claim 1, wherein R1 and R2 together form a 5-membered ring containing one or two C=O, and such ring is optionally substituted with H, OH, F, Cl, Br, I, CN, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, phenyl or phenoxy.

8. The molecule of claim 1, wherein each of R4, R5, R6, and R7 is independently H, F, Cl, or a C1-C6 alkyl.

9. The molecule of claim 1, wherein R3 is a substituted phenyl with one or more H, F, Cl, Br, I, C1-C6 alkyl, C1-C6 haloalkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 haloalkenyl, (C1-C6 alkyl)O(C1-C6 alkyl), C1-C6 alkoxy, C1-C6 haloalkoxy, or wherein two adjacent substituents form a 5- or 6-membered saturated or unsaturated, hydrocarbyl link, which may contain one or more heteroatoms selected from nitrogen, sulfur, and oxygen, and wherein said hydrocarbyl link may optionally be substituted with one or more substituents independently selected fromH, F, Cl, Br, I, CN, OH, SH, NO2, NRxRy, C1-C6 alkyl, C1-C6 haloalkyl, C1-C6 alkoxy, C1-C6 haloalkoxy, S(=O)n(C1-C6 alkyl), and S(=O)n(C1-C6 haloalkyl).

10. The molecule of claim 1 having a structure selected from compounds listed in Table 1

11. A process to apply a molecule according to claim 1 comprising,

applying a molecule according to claim 1, to an area to control a pest, in an amount sufficient to control such pest.

12. A process according to claim 11, wherein said pest is beet armyworm (BAW), cabbage looper (CL), or yellow fever mosquito (YFM).

13. A molecule that is a pesticidally acceptable acid addition salt, a salt derivative, a solvate, or an ester derivative, of a molecule according to claim 1.

14. A molecule according to claim 1 wherein at least one H is 2H or at least one C is 14C.

15. A composition comprising a molecule according to claim 1 and at least one other compound having insecticidal, herbicidal, acaricidal, nematicidal, or fungicidal activity.

16. A composition comprising a molecule according to claim 1 and a seed.

17. A process comprising applying a molecule according to claim 1 to a genetically modified plant, or genetically-modified seed, which has been genetically modified to express one or more specialized traits.

18. A process comprising: orally administering; or topically applying; a molecule according to claim 1, to a non-human animal, to control endoparasites, ectoparasites, or both.